Results 21 to 30 of about 135,124 (268)

Synthesis and Thermal Behaviour of Calcium Alkyl Phosphates as Bioceramic Precursors

open access: yesCeramics, 2022
Powders of alkyl phosphoric acids and calcium alkyl phosphates with various alkyl chains (butyl, octyl, and dodecyl) have been synthesized. The resulting powders were characterized by X-ray phase analysis, electron microscopy, and thermal analysis.
Andrey Tikhonov, Valery Putlayev
doaj   +1 more source

The alkyl moieties in wax esters and alkyl diacyl glycerols af sharks

open access: yesJournal of Lipid Research, 1971
The alkyl moieties in wax esters and alkyl diacyl glycerols from the liver of the dogfish, soupfin shark, and silky shark are almost exclusively saturated and monounsaturated, the main alkyl moieties being the C16 and C18 chains in both lipid classes ...
FRIEDRICH SPENER, HELMUT K. MANGOLD
doaj   +1 more source

Alkylating Agents Stronger than Alkyl Triflates [PDF]

open access: yesJournal of the American Chemical Society, 2004
A new class of potent electrophilic "R(+)" alkylating agents has been developed using weakly nucleophilic carborane anions as leaving groups. These reagents, R(CHB(11)Me(5)X(6)) (R = Me, Et, and i-Pr; X = Cl, Br), are prepared via metathesis reactions with conventional alkylating agents such as alkyl triflates, using the high oxophilicity of silylium ...
Kato, Tsuyoshi   +4 more
openaire   +4 more sources

Antibacterial activity of alkyl gallates is a combination of direct targeting of FtsZ and permeabilization of bacterial membranes

open access: yesFrontiers in Microbiology, 2015
Alkyl gallates are compounds with reported antibacterial activity. One of the modes of action is binding of the alkyl gallates to the bacterial membrane and interference with membrane integrity.
Ewa eKról   +6 more
doaj   +1 more source

Multiple Beneficial Health Effects of Natural Alkylglycerols from Shark Liver Oil

open access: yesMarine Drugs, 2010
Alkylglycerols (alkyl-Gro) are ether lipids abundant in the liver of some elasmobranch fish species such as ratfishes and some sharks. Shark liver oil from Centrophorus squamosus (SLO), or alkyl-Gro mix from this source, have several in vivo biological ...
Alain B. Legrand   +5 more
doaj   +1 more source

New insight into the spatiotemporal variability and source apportionments of C1–C4 alkyl nitrates in Hong Kong [PDF]

open access: yesAtmospheric Chemistry and Physics, 2016
C1–C4 alkyl nitrates (RONO2) were measured concurrently at a mountain site, Tai Mo Shan (TMS), and an urban site, Tsuen Wan (TW), at the base of the same mountain in Hong Kong from September to November 2010. Although the levels of parent hydrocarbons
Z. Ling   +8 more
doaj   +1 more source

Mono-Alkyl-Substituted Phosphinoboranes (HRP–BH2–NMe3) as Precursors for Poly(alkylphosphinoborane)s: Improved Synthesis and Comparative Study

open access: yesInorganics, 2023
A new synthetic pathway to various mono-alkyl-substituted phosphinoboranes HRP–BH2–NMe3 has been developed. The new synthetic route starting from alkyl halides and NaPH2 followed by metalation and salt metathesis is performed in a one-pot procedure and ...
Felix Lehnfeld   +3 more
doaj   +1 more source

Alkylation of Dihydrofullerenes [PDF]

open access: yesThe Journal of Organic Chemistry, 2002
The fulleride dianions C(60)(2-) and C(70)(2-) were generated by deprotonation of the corresponding hydrogenated fullerenes, 1,2-C(60)H(2) and 1,2-C(70)H(2). These anions were prepared in the presence of a variety of alkylating agents, and mono- or dialkylated products were obtained. Alkylation was not successful with sulfonate ester alkylating agents.
Mark S, Meier   +4 more
openaire   +2 more sources

Ketones from aldehydes via alkyl C(sp3)−H functionalization under photoredox cooperative NHC/palladium catalysis

open access: yesNature Communications, 2023
Direct synthesis of ketones from aldehydes features high atom- and step-economy. Yet, the coupling of aldehydes with unactivated alkyl C(sp3)-H remains challenging.
Hai-Ying Wang   +4 more
doaj   +1 more source

Mechanistic Insights into Nickamine-catalyzed Alkyl-Alkyl Cross-coupling Reactions

open access: yesCHIMIA, 2014
Within the last decades the transition metal-catalyzed cross-coupling of non-activated alkyl halides has significantly progressed. Within the context of alkyl-alkyl cross-coupling, first row transition metals spanning from iron, over cobalt ...
Jan Breitenfeld, Xile Hu
doaj   +1 more source

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