Results 171 to 180 of about 166,984 (347)
Ferrocenylphosphine-imine ligands for Pd-catalyzed asymmetric allylic alkylation
Ferrocenylphosphine-imine ligands 6 derived front (R,S)-PPFNH2-R 5 and a variety of benzaldehydes were applied in the Pd-catalyzed asymmetric allylic alkylation of 1,3-diphenylprop-2-en-1-yl acetate 7a or pivalate 7b with dimethyl malonate.
Wang, JW +6 more
core
Copper(I) hydride complexes often exhibit diverse aggregation behavior that can profoundly influence their structure and reactivity. In this study we use a combined experimental and computational approach to identify key structural an electronic factors that govern aggregation in PNNP dicopperhydride complexes.
Roel Laurentius Maria Bienenmann +5 more
wiley +1 more source
Influence of Acidity Properties on the Hβ Catalytic Performance of the Olefin Alkylation Thiophenic Sulfur in Gasoline Zekai Zhang1,2, Xionglei Niu1,2, Xiangxue Zhu1, Shenglin Liu1, Longya Xu1 1.
张泽凯 +4 more
core
Pharmaceuticals Made with Hydrogen: A Sustainable and Efficient Approach Using Flow Synthesis
We demonstrate a sustainable strategy for pharmaceutical manufacturing by combining hydrogen, heterogeneous catalysis, and continuous flow synthesis. The development of novel catalysts and their application in a multi‐step synthesis of donepezil enabled a highly productive process with no intermediate purification.
Shū Kobayashi, Haruro Ishitani
wiley +1 more source
α-Alkylated α-amino acids reduce the aggregation of unfolded peptides. [PDF]
Zheng H, Newberry RW.
europepmc +1 more source
ABSTRACT Fluorouracil‐platinum(IV) prodrugs represent a novel class of multimechanistic chemotherapeutics with enhanced anticancer potential. The prodrugs PtIVP‐5FUMeOBut and PtIV56‐5FUMeOBut were actualized by derivatising the clinical drug 5‐fluorouracil (5FU) and coordinating it to platinum(IV) complexes, leveraging the established cytotoxicity of ...
Maria George Elias +9 more
wiley +1 more source
Nano-cobalt anchored on chitosan-derived N-doped porous carbon: an efficient catalyst for α-alkylation of ketones with alcohols <i>via</i> borrowing hydrogen. [PDF]
Zhang Z +5 more
europepmc +1 more source
Monosubstituted N‐arylhydroxylamines represent a unique subclass of hydroxylamines that act as pivotal intermediates in redox transformations and as versatile platforms for further synthetic transformations. They serve as key building blocks in the synthesis of architecturally complex heterocycles and other valuable organic compounds.
Michael G. Kallitsakis +2 more
wiley +1 more source
Enantioselective organocatalytic radical alkylation enabled by photoexcitation. [PDF]
Song Y +6 more
europepmc +1 more source

