Room-Temperature Metal-Catalyzed Hydrogen Borrowing Alkylation. [PDF]
Bailey EP, Donohoe TJ, Smith MD.
europepmc +1 more source
Mechanochemical Amidation Mediated by 1,1’‐Oxalyldiimidazole for the Synthesis of Agrochemicals
Mechanochemical amidation using 1,1'‐oxalyldiimidazole (ODI) overcomes limitations of 1,1’‐carbonyl diimidazole (CDI) as coupling agent by enabling the efficient mechanochemical synthesis of three marketed agrochemicals from deactivated carboxylic acids.
Andrea Casagrande +6 more
wiley +1 more source
Chemoselective Alkylating Esterification of Thiophosphinic Acids: An Experimental and Theoretical Study. [PDF]
Keglevich G +6 more
europepmc +1 more source
Titanium‐Catalyzed Diastereoselective Keto‐ and Iminonitrile Cyclizations
The titanium(III)‐catalyzed diastereoselective cyclization of readily‐available substituted ketonitriles gives cyclopentanones in good yield and stereoselectivity. Subsequent 1,2‐addition allows the preparation of cyclopentyls with three consecutive stereocenters.
Christoph Kern +4 more
wiley +1 more source
Efficient Approaches to Six-Membered Polyazacyclic Compounds-Part 3: C-H Functionalization of Heterocycles. [PDF]
Titova YY, Ivanov AV.
europepmc +1 more source
Azidophosphonamido Rhodium(I) and Iridium(I) Complexes: Synthesis, Properties, and Linkage Isomerism
A family of azidophosphonamido ligands and their corresponding rhodium(I) and iridium(I) complexes were synthesized. The rich reaction chemistry of these species revealed unusual linkage isomerization processes and bonding motifs. M = Rh, Ir; Mes = 2,4,6‐Me3C6H2. ABSTRACT A series of azidophosphonamido rhodium(I) and iridium(I) complexes ([iPr2P(N3R)NR]
Emily L. Trew +3 more
wiley +1 more source
Isolation and Characterization of St-CRPs: Cysteine-Rich Peptides from the Arctic Marine Ascidian <i>Synoicum turgens</i>. [PDF]
Hansen IKØ +7 more
europepmc +1 more source
Synthesis of Oligonucleotide Conjugates Employing a Diselenide Linker
ABSTRACT In this study, we report the synthesis of an alkylene linker containing a terminal 2‐cyanoethyl protected selenium functionality for coupling at the 5'‐end of an oligonucleotide by solid phase synthesis for the preparation of oligonucleotide conjugates.
Shivam Tikoo +2 more
wiley +1 more source
Total Syntheses of (+)-Hyperbeanols A-C, (+)-Hyperpatulol A, and (-)-Hypercohone G, as Well as Structure Revision of Hyperpatulol A, and Hyperbeanol B. [PDF]
Liu X +6 more
europepmc +1 more source
Stereochemical Control in the Matteson Reaction
The Matteson homologation is a highly versatile method for the stereoselective insertion of carbenoids into boronic esters. Through iterative application of the process, complex chiral molecules can be synthesized. The stereoselectivity of the reaction is determined by a chiral diol incorporated in the boronic ester.
Hae Mo Lee, Christoph Hirschhäuser
wiley +1 more source

