Results 161 to 170 of about 107,279 (237)

Flavin Catalysts in Organic Synthesis

Angewandte Chemie, EarlyView.
Flavins and their congeners are potent catalysts for organic synthesis inspired by enzymatic transformations. In addition to catalysis in the flavin ground state via covalent intermediates, the excited singlet and triplet states unlock applications including photooxidation, photoreduction, and energy transfer via sensitization.
Jan Freudenberg, Golo Storch
wiley   +2 more sources

Cyanamide-Induced Desulfhydration Enables Access to α,β-Dehydropeptides. [PDF]

Org Lett
Yang Y, Xue S, Moreira R, van der Donk WA.   +3 more
europepmc   +1 more source

Photochemical Reaction Discovery Enabled by the Dynamic Speciation of Copper Complexes

Angewandte Chemie, EarlyView.
A strategy for accelerated photochemical reaction discovery is reported that harnesses the dynamic speciation of copper complexes, driven by their labile metal–ligand bonds. This platform simplifies reaction screening by combining an earth‐abundant copper(II) salt with commercially available ligands, which reversibly generate multiple catalytic species
Alessio Regni, Siyu Liang, Supreeta Sen, Hailey Hendricks, Xijue Wu, Matthew V. Pecoraro, Jose B. Roque   +6 more
wiley   +2 more sources

The Catalytic Asymmetric Alkylation of Olefins with Alcohol Derivatives. [PDF]

J Am Chem Soc
Debie LM, Gotta T, Turberg M, Nöthling N, List B.   +4 more
europepmc   +1 more source

Influence of Acidity Properties on the Hβ Catalytic Performance of the Olefin Alkylation Thiophenic Sulfur in Gasoline

, 2006
Influence of Acidity Properties on the Hβ Catalytic Performance of the Olefin Alkylation Thiophenic Sulfur in Gasoline Zekai Zhang1,2, Xionglei Niu1,2, Xiangxue Zhu1, Shenglin Liu1, Longya Xu1 1.
张泽凯, 徐龙伢, 刘盛林, 朱向嚐, 牛雄雷   +4 more
core  

Temperature-Dependent Microstructural Evolution of Seed-Assisted Low-Template ZSM-5 and Its Catalytic Behavior in Benzene Alkylation with Methanol. [PDF]

Molecules
Wu S, Shi Y, Zheng Q, Yuan J, Xiang Y, Jiang Y, Zhang J, Zhou A, Guo X.   +8 more
europepmc   +1 more source

Peripheral editing of polyols to chiral alkanes. [PDF]

Nat Commun
Saadane A, Hansjacob P, Van Laethem S, Audet F, Evano G.   +4 more
europepmc   +1 more source

Phosphonium Ions as Activating Groups for the Selective Alkylation of Pyridines and Polyazines. [PDF]

J Am Chem Soc
Brunner DA, Thomas DC, Steenback KR, Rozema SD, McNally A.   +4 more
europepmc   +1 more source

Deprotonation and Alkylation of Weakly Acidic C(sp3)─H Bonds Through In Situ Generation of a Strong Hydride Base From 1,1,3,3‐Tetramethyldisiloxane and Potassium tert‐Butoxide

Angewandte Chemie, EarlyView.
The use of 1,1,3,3‐tetramethyldisiloxane (TMDSO) and potassium tert‐butoxide enables direct alkylation of weakly acidic carbon–hydrogen bonds with alkyl halides. Experimental and computational studies support the formation of a substrate‐associated hydride‐like base, providing a single‐step alternative to the classical deprotonation and electrophile ...
Piers St. Onge, Brandon White, Han Yao, Travis Dudding, Stephen G. Newman   +4 more
wiley   +1 more source

Coupling Polyolefin Conversion and Methanol Reduction for C₉-C₁₀ Alkylaromatic Production. [PDF]

Angew Chem Int Ed Engl
Li SR, Smith RL, Kozinski JA, Fang Z.
europepmc   +1 more source