Results 101 to 110 of about 165,943,760 (239)

Borylcyclopropanes: Synthetic Strategies and Applications

Angewandte Chemie, Volume 138, Issue 37, 7 September 2026.
Borylcyclopropanes (cyclopropanes bearing a boron substituent) sit at the intersection of two privileged frameworks in synthesis. This review provides the first exhaustive survey of their chemistry, spanning metal–carbene, nucleophilic cyclization, radical, hydroboration, and C─H activation routes, and documenting applications in medicinal chemistry ...
Aiza A. Butt, Joseph M. Ready
wiley   +2 more sources

Alkylation of Benzene with Ethanol over ZSM-5 Based La–P Catalysts

Bulletin of Chemical Reaction Engineering & Catalysis
Benzene ethylation in the presence of HZSM-5 zeolites is a promising method for producing ethylbenzene. This study examined the effects of modifying lanthanum and phosphorus as additives to the HZSM-5 catalyst, tested in the temperature range of 300-500 °
Sabit Eyyub Mamedov, Aynur Abulfat Iskenderova, Eyyub Sabit Mammadov, Nargiz Firudin Akhmedova, Fuad Shamsaddin Kerimli, Sevda Baba Ismayilova   +5 more
doaj   +1 more source

Synthesis of linear phenyldodecanes by the alkylation of benzene with 1-dodecene over non-zeolitic catalysts

, 2002
Linear alkylbenzenes (LAB) are typically manufactured by the alkylation of benzene and α-olefin, employing HF or AlCl3 as catalyst. LAB are the precursors of linear alkylbenzene sulphonates (LABS) used in a variety of industries.
Yadav, G. D., Doshi, N. S.
core   +1 more source

Bolapolyphiles With Bulky Carbosilane‐Based Lateral Groups—Reticular Design of Liquid Crystalline Pentagonal Honeycombs

Chemistry – A European Journal, EarlyView.
T‐shaped bolapolyphiles with highly branched carbosilane‐based side‐groups self‐assemble into liquid crystalline honeycombs composed of type‐2 pentagonal prismatic cells and p2gg plane group symmetry. ABSTRACT Periodic pentagon tessellations are rarely observed in self‐assembled molecular systems.
Christian Anders, Matthias Wagner, Silvio Poppe, Carsten Tschierske   +3 more
wiley   +1 more source

Design and optoelectronic profiling of a semicrystalline thiophene–phenylene copolymer for advanced organic electronics

Polymer International, EarlyView.
A new semicrystalline copolymer, PTBT‐3OBu, was synthesized. Intramolecular S···O conformational locks induce high backbone planarity, promoting strong interchain coupling and molecular ordering in thin films, seen in an optical red shift. This synergy between planarity and semicrystalline morphology is promising for photovoltaic and electrochromic ...
Sandra Lúcia Nogueira, Silésia de Fátima Curcino da Silva, Giovani Bortolini Oliveira, Bruno Souza Zanatta, Thibaut Jarrosson, Françoise Serein‐Spirau, Alexandre Marletta, Raigna Augusta da Silva   +7 more
wiley   +1 more source

Smart cellulose‐based room temperature phosphorescent materials: From mechanisms to construction strategies and applications

Smart Molecules, EarlyView.
This review elucidates the photophysical mechanisms of cellulose‐based room temperature phosphorescent materials and systematically outlines their construction strategies, such as cluster emission center engineering. This article demonstrates their applications in fields like information encryption and bioimaging, and looks ahead to the core challenges
Shasha Wu, Yifan Zhou, Wanjin Wu, Yan Tang, Mengfan Jing, Jianyu Zhang, Haoke Zhang, Zheng Zhao, Junwei Wang, Laurent Maron, Lijie Liu   +10 more
wiley   +1 more source

Copper(II/III) Redox Couple Enables C─H Methylation via a Radical Mechanism Analogous to SAM Enzymes

Angewandte Chemie, Volume 138, Issue 36, 1 September 2026.
Biological C–H methylation proceeds through radical pathways mediated by one‐electron redox cofactors, yet no synthetic model has reproduced this reactivity. Here, we report the first isolable Cu(II/III)–methyl complexes that mediate C–H methylation through hydrogen atom transfer and methyl radical rebound.
Emily N. Doss, Curtis E. Moore, Shiyu Zhang   +2 more
wiley   +2 more sources

Advances in Unconventional and Sustainable Synthetic Approaches to Benzopyran Scaffolds

The Chemical Record, EarlyView.
This review provides a comprehensive and critical analysis of low‐impact synthetic methodologies reported in the last 8 years (2018–2026) for the construction of benzopyran‐derived scaffolds, such as coumarins, flavones, chromones, chromenes, and chromanes. The benzopyran scaffold is a versatile family of heterocycles found in a wide range of bioactive
Nathalia B. Sá, Patrick C. Nobre, Isabelly O. Ferreira, Juliano B. Azeredo, Vanessa Nascimento   +4 more
wiley   +1 more source

Implementation of Dynamic Simulation to Study the Deviation Consequences Along a Complex Process

Chemical Engineering Transactions, 2019
The dynamic simulation of a chemical process is carried out to quantify the potential consequences that may arise in response to a deviation propagation. For this purpose, a case study is based on the industrial alkylation of benzene by propene to cumene
Carlos Murillo, Nelly Olivier-Maget, Nadine Gabas   +2 more
doaj   +1 more source

Oxaziridines: Versatile Reagents in Modern Organic Synthesis

The Chemical Record, EarlyView.
Being capable of transferring an O atom and N‐group/atom, oxaziridines are considered multitasking agents. These are employed for diverse organic transformations, such as epoxidation of olefins, α‐ and γ‐hydroxylation/amination of carbonyl compounds, oxidation of sulfides, [3+2]cycloaddition with unsaturated systems.
Ajeet Chandra, Subba Rao Cheekatla, Keshaba Nanda Parida   +2 more
wiley   +1 more source