Results 41 to 50 of about 45,374 (213)

Modulation of metal species as control point for Ni-catalyzed stereodivergent semihydrogenation of alkynes with water

open access: yesNature Communications, 2023
Generally, transition metal-catalyzed stereodivergent transfer semihydrogenation of alkynes realized regulation of stereoselectivity by a Z to E isomerization process.
Yuanqi Wu   +9 more
doaj   +1 more source

Bismuth Subnitrate-Catalyzed Markovnikov-Type Alkyne Hydrations under Batch and Continuous Flow Conditions

open access: yesMolecules, 2021
Bismuth subnitrate is reported herein as a simple and efficient catalyst for the atom-economical synthesis of methyl ketones via Markovnikov-type alkyne hydration.
Zsanett Szécsényi   +2 more
doaj   +1 more source

Síntese de 1,3-diinos via acoplamento de acetilenos terminais catalisada por CuI sob irradiação de micro-ondas [PDF]

open access: yes, 2015
Dissertação (mestrado) - Universidade Federal de Santa Catarina, Centro de Ciências Físicas e Matemáticas, Programa de Pós-Graduação em Química, Florianópolis, 2015.No presente trabalho, desenvolveu-se uma nova metodologia sintética eficiente, simples e ...
Bettanin, Luana
core  

Copper-Catalyzed Regioselective [4+2] Annulations between Diaryliodonium Salts and Alkynes: Design, Development, and Applications [PDF]

open access: yes, 2022
Herein, a new reaction pattern of diaryliodonium salts was reported as novelty oxa-1,4-dipoles to undergo [4+2] cycloaddition reactions with alkynes.
Congdi, Zhang   +5 more
core   +2 more sources

Oxidative [3+2]Cycloaddition of Alkynylphosphonates with Heterocyclic N-Imines: Synthesis of Pyrazolo[1,5-a]Pyridine-3-phosphonates

open access: yesMolecules, 2022
A series of pyrazolo[1,5-a]pyridine-3-ylphosphonates were prepared with moderate to good yields by the oxidative [3+2]cycloaddition of 2-subtituted ethynylphosphonates with in situ generated pyridinium-N-imines and their annulated analogs.
Igor Philippov   +3 more
doaj   +1 more source

Photocatalytic Cycloaddition Reaction of Triarylphosphines with Alkynes Forming Cyclic Phosphonium Salts [PDF]

open access: yes, 2021
Herein reported is a photocatalytic cycloaddition reaction of triarylphosphines with alkynes. Phosphonium salts of unique bicyclic structures are synthesized through a radical pathway under mild reaction conditions. The phosphonium salts are subjected to
Yusuke, Masuda   +2 more
core   +2 more sources

Intermolecular Hydroaminoalkylation of Alkynes

open access: yesChemistry – A European Journal, 2021
AbstractIntermolecular hydroaminoalkylation reactions of alkynes with secondary amines, which selectively give access to allylic amines with E configuration of the alkene unit, are achieved in the presence of titanium catalysts. Successful reactions of symmetrically substituted diaryl‐ and dialkylalkynes as well as a terminal alkyne take place with N ...
Tobias Kaper   +6 more
openaire   +2 more sources

Electrochemical cyclization of alkynes to construct five-membered nitrogen-heterocyclic rings

open access: yesBeilstein Journal of Organic Chemistry
Organic five-membered rings have shown significant applications in the fields of organic synthesis, natural products, organic materials and pharmaceuticals for their unique characteristics. Electrochemical construction of five-membered rings from alkynes
Lifen Peng   +10 more
doaj   +1 more source

The evolution of fundamental concepts in organic chemistry: Hydrocarbons in Iranian secondary school chemistry textbooks and their information content and importance based on shannon entropy [PDF]

open access: yesپژوهش در آموزش شیمی
Background and Objective: This study examines the changes in the basic concepts of the chemistry of different branches of hydrocarbons (alkanes, alkenes, alkynes, and aromatics) in high school chemistry textbooks from 1971 to 2021.
Doost Mohammad Samiei Paghaleh   +1 more
doaj   +1 more source

Hydroamination of alkynes catalyzed by NHC-Gold(I) complexes: the non-monotonic effect of substituted arylamines on the catalyst activity

open access: yesFrontiers in Chemistry, 2023
Imines are valuable key compounds for synthesizing several nitrogen-containing molecules used in biological and industrial fields. They have been obtained, as highly regioselective Markovnikov products, by reacting several alkynes with arylamines in the ...
Marco Sirignano   +6 more
doaj   +1 more source

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