Results 61 to 70 of about 41,386 (303)
Nature Communications, 2018 Converting alkynes into alkenes with high stereoselectivity via two consecutive C-C bond forming steps is a desirable process, yet very challenging. Here, the authors describe a dual photoredox-nickel catalytic system for the regio- and syn-selective ...
Lei Guo +4 more
doaj +1 more source
Catalytic, Z-Selective, Semi-Hydrogenation of Alkynes with a Zinc–Anilide Complex
, 2022 The reversible activation of dihydrogen with a molecular zinc anilide complex is reported. The mechanism of this reaction has been probed through stoichiometric experiments and DFT calculations. The combined evidence suggests that H2 activation occurs by
Mark, Crimmin +4 more
core +1 more source
In Situ Amine Formation to Modulate MOF‐Derived PdIn N‐Doped Carbon Catalysts
Advanced Materials, EarlyView.An amine‐assisted approach converts PdIn‐MOF into PdIn intermetallic nanoparticles embedded in N‐doped carbon. In situ‐generated amines trigger early Pd nucleation, producing smaller PdIn domains than direct pyrolysis. Amine sterics and basicity tune composition and particle size, while solvent and amine co‐determine textural features.
Gonzalo Egea +9 more
wiley +1 more source
Advanced Materials, EarlyView.Controlling the protein corona formation onto carbon nanomaterials (CNMs) enhances their functionalities as platforms for cancer theranostics. Here, we reviewed the effects of the intrinsic and acquired properties of CNMs on protein corona formation, the consequent biological and toxicological outcomes, and the strategies to reshape corona formation ...
Yajuan Zou +5 more
wiley +1 more source
Rhodium/Ming-Phos-catalyzed asymmetric annulation reaction of silacyclobutanes with terminal alkynes
Green Synthesis and CatalysisAsymmetric ring-expansion reactions of silacyclobutanes (SCBs) with alkynes have evolved as one of the powerful protocols for the construction of silicon-stereogenic compounds.
Yue Sun +4 more
doaj +1 more source
Molbank, 2013 Functionalizable salen derivative, 6,6'-(1E,1'E)-((1R,2R)-1,2-diphenylethane-1,2-diyl)bis(azan-1-yl-1-ylidene)bis(methan-1-yl-1-ylidene)bis(2-tert-butyl-4-((trimethylsilyl) ethyn-yl)phenol) (3), was synthesized by condensation between (1R,2R)-1,
David Díaz Díaz +4 more
doaj +1 more source
Synthesis of Tetrasubstituted Pyrroles from Terminal Alkynes and Imines
, 2013 Tetrasubstituted pyrroles can be obtained via the reaction of terminal alkynes and Imines using (BuLi)-Bu-n as the base In one step with high chemoselectivity (method 1).
Wu, Fan +5 more
core +1 more source
Relative Performance of Alkynes in Copper-Catalyzed Azide–Alkyne Cycloaddition [PDF]
Bioconjugate Chemistry, 2013 Copper-catalyzed azide-alkyne cycloaddition (CuAAC) has found numerous applications in a variety of fields. We report here only modest differences in the reactivity of various classes of terminal alkynes under typical bioconjugative and preparative organic conditions.
Alexander A, Kislukhin +3 more
openaire +2 more sources
Phase Engineering of Atomically Precise Nanoclusters (APNCs) of Gold and Beyond
Advanced Materials, EarlyView.Engineering the structural phase of materials is of paramount importance for both fundamental research and practical applications. In this Review, we summarize the recent progress in controlling the phases of atomically precise nanoclusters (APNCs) of gold, silver and copper, as well as bimetallic systems. The phase‐enabled material properties of APNCs
Yitong Wang +4 more
wiley +1 more source
Cobalt-catalyzed hydrothiolation of alkynes for the diverse synthesis of branched alkenyl sulfides
Nature CommunicationsAlkenyl sulfides have gained increasing prominence in medicinal chemistry and materials. Hydrothiolation of alkynes for the diverse synthesis of alkenyl sulfides is an appealing method.
Jiale Ying, Yan Tan, Zhan Lu
doaj +1 more source