Results 81 to 90 of about 1,533 (254)

Phase‐Pure 2D Interfacial Perovskite Passivation for Stable and Efficient Photovoltaics

open access: yesCarbon Energy, EarlyView.
Phase‐pure 2D interfacial passivation eliminates mixed‐phase energetic disorder, establishes favorable band alignment, and suppresses interfacial non‐radiative recombination. This review elucidates deterministic phase‐purity control, defect and lattice reconstruction mechanisms, and scalable manufacturing strategies, highlighting how phase‐pure 2D/3D ...
Ming‐Xin Li   +9 more
wiley   +1 more source

Boosting Electron‐Hole Charge Separation in CO2 Photoreduction through Fluoroporphyrin‐Linked Nickel(II)‐Acetylide Frameworks

open access: yesCarbon Energy, EarlyView.
A NiII‐acetylide framework, H2TFPP‐Ni‐AF, demonstrates outstanding photocatalytic CO2 reduction performance: 13.16 mmol h−1 g−1 of CO with 97.9% selectivity. Synergistic interactions, including d‐p orbital hybridization within NiII‐bis(acetylide) moieties ( − C ≡ C−NiII(PBu3)2 − C ≡ C − ) and the efficient charge transport afforded by π‐conjugated ...
Lifen Chen   +6 more
wiley   +1 more source

Sodium Tetraazidoaurate(III)—From Na[AuCl4]·2H2O to Na[Au(N3)4] and Beyond One Step at a Time

open access: yesChemistry – A European Journal, EarlyView.
Novel sodium chlorido‐/azidoaurate(III) dihydrates Na[AuCl4–x(N3)x]·2H2O (x = 0, 1, 2, 3, 4) provide the first example of a complete series of gradual substitution on tetramer complex anions to be described. Controlled dehydration of Na[Au(N3)4]·2H2O leads to Na[Au(N3)4]·H2O and Na[Au(N3)4], the latter being a highly explosive material.
Mehmet Somer   +10 more
wiley   +1 more source

The Osmium Isotope Signature of Phanerozoic Large Igneous Provinces

open access: yesGeophysical Monograph Series, Page 229-246., 2021

Exploring the links between Large Igneous Provinces and dramatic environmental impact

An emerging consensus suggests that Large Igneous Provinces (LIPs) and Silicic LIPs (SLIPs) are a significant driver of dramatic global environmental and biological changes, including mass extinctions.
Alexander J. Dickson   +2 more
wiley  

+3 more sources

Unraveling the local stress corrosion cracking behavior of Alloy 690 plug in a high-temperature concentrated alkaline solution

open access: yesCorrosion Communications
The stress corrosion cracking (SCC) performance of the sealed Alloy 690 plugs was investigated in 350 °C deoxygenated concentrated alkaline solution. Sealing was used to expose only the inner surface of the plug, preventing direct contact between the ...
Baoliang Cheng   +8 more
doaj   +1 more source

Digital holographic reconstruction detection of localized corrosion arising from scratches [PDF]

open access: yesJournal of the Serbian Chemical Society, 2010
In this study, electrochemical methods and the digital holographic reconstruction technique were combined to detect the localized scratch-induced corrosion process of Alloy 690 in 0.50 mol dm-3 H2SO4 containing 0.10 mol dm-3 NaCl.
LIANG WANG   +6 more
doaj  

Programming the Optoelectronic Properties of Atomically Precise Gold Nanoclusters Using the Conformational Landscape of Intrinsically Disordered Proteins

open access: yesChemistry – A European Journal, EarlyView.
ABSTRACT The rational design of hybrid nanomaterials with precisely controlled properties remains a central challenge in materials science. While atomically precise gold nanoclusters (Au‐NCs) offer molecule‐like control over a metallic core, tuning their optoelectronic behavior via surface engineering is often empirically driven.
Santiago Rodriguez   +15 more
wiley   +1 more source

Accessing Sn≥2 States of a TADF Emitter by Femtosecond NIR Spectroscopy

open access: yesChemistry – A European Journal, EarlyView.
The depicted thermally activated delayed fluorescence (TADF) emitter was studied by femtosecond near‐infrared (NIR) spectroscopy. A prominent NIR transition was shown to be strongly solvent‐dependent, with implication for intersystem crossing in the compound.
Wiebke Haselbach   +7 more
wiley   +1 more source

Corrosion and Anodic Oxidation of Alloy 690 in Simulated Primary Coolant of a Small Modular Reactor Studied by In Situ Electrochemical Impedance Spectroscopy

open access: yesMetals
The effect of KOH concentration as a boron-free coolant for prospective use in Small Modular Reactors (SMRs) on the corrosion of Alloy 690 is studied by in situ impedance spectroscopy at 280 °C/9 MPa during 168 h exposure in a flow-through cell connected
Martin Bojinov   +2 more
doaj   +1 more source

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