Low‐dimensional materials (0D, 1D, and 2D) exhibit unique electronic and physicochemical properties, enabling advanced nanoelectronic and optoelectronic devices. Mixed‐dimensional heterostructures combine these materials to enhance functionality.
Qaisar Alam +3 more
wiley +1 more source
Solvent-Controlled Chemoselectivity in Brønsted Acidic Deep Eutectic Mixtures: A Metal-Free One-Pot Cascade Meyer-Schuster/C-P Bond Formation. [PDF]
Morís-Menéndez G +4 more
europepmc +1 more source
A smart gel electrolyte with thermal shutdown capability has been proposed enabled by a two‐step cross‐linking strategy, which preserves a high density of unreacted double bonds at room temperature. This strategy brings negligible degradation to room temperature electrochemical performance, while under thermal abuse conditions above 115 °C, the gel ...
Yihan Wu +6 more
wiley +1 more source
Three-site cycloadditions within one reaction intermediate with site-selectivity controlled by electronic and size bias. [PDF]
Maitra C +6 more
europepmc +1 more source
Contrasting sustainable biomass with depleting petroleum resources, this review charts the evolutionary timeline of lignin‐based TENGs. We systematically evaluate their fundamental mechanisms, enhancement strategies, and applications in green self‐powered electronics.
Yuxin Yang +9 more
wiley +1 more source
Unwrapping the Dodecaborane Core: Structure, Electronic Properties, and Chemical Reactivity Across the Complete [B<sub>12</sub>I<sub><i>n</i></sub>]<sup>-</sup> Series (<i>n</i> = 11-1). [PDF]
Shao Q +12 more
europepmc +1 more source
Oxidant‐Expedited Synthesis of H‐Phosphonates
An exceptionally mild method for synthesis of alkyl and aryl H‐phosphonates from phosphites is reported, requiring only water and O2 (including air) as reagents. Mechanistic experiments indicate that the role of O2 (and other oxidants) in the transformation is to promote a radical mechanism, and that H2O functions to provide both the hydrogen and the ...
Dara T. Curran +4 more
wiley +1 more source
General and efficient access to homoallyl amines <i>via</i> single-electron-transfer reduction-induced E1cb elimination reaction. [PDF]
Ye Z, Fan B, Zhang L, Xie R, Fang Y.
europepmc +1 more source
Synthetic Strategies for the Construction of Cyclobutane‐Fused Heterocycles
Cyclobutane‐fused heterocycles are important motifs commonly present in bioactive compounds, recognized for their rigid 3D structures that confer unique properties. However, synthesizing these compounds remains challenging. This review discusses current methods for their synthesis, such as photochemical, metal‐catalyzed, and Lewis acid‐mediated [2 + 2]
Michela Vargiu +2 more
wiley +1 more source
Chelation‐Assisted Metal‐Catalyzed Ligation and Cleavage Reactions for Chemical Biology
Chelation‐assisted transition metal catalysis has emerged as a promising complement to bioorthogonal click chemistry for studying biological processes. By pre‐organizing catalytic metal centers, designed coordinating substrates enhance reactivity and biocompatibility, enabling site‐selective ligation and decaging reactions in complex biological media ...
Emilie Plantiveau +3 more
wiley +1 more source

