Results 161 to 170 of about 1,621,772 (233)

Introduction of a Double‐Headed Nucleotide Into G‐Quadruplex DNA: Position‐Dependent Stabilization and Structural Insights

Chemistry – A European Journal, EarlyView.
A double‐headed bis‐guanine (G) nucleotide (GG) was evaluated as a noncanonical building block in G‐quadruplexes (G4s). Biophysical and computational analyses reveal that GG can directly participate in G‐tetrads and strongly stabilize G4s in a position‐ and topology‐dependent manner. These findings establish design rules for using GG to engineer highly
Krista Urup, Peter Reinholdt, Kasper Munch Beck, Michael Petersen, Jean‐Louis Mergny, Poul Nielsen   +5 more
wiley   +1 more source

Putative binding of <i>Piper betle</i> L. phytochemicals to mannitol pathway enzymes during sporulation of <i>Eimeria tenella</i>. [PDF]

Vet Anim Sci
Wibowo S, Hamid PH, Ristanti R, Nugroho HA, Nashrulloh MM, Nuringtyas TR, Ferdian PR, Amalia RLR, Caro TM, Maulydia NB, Kusumarini S, Wardhana AH, Cahyadi M, Matsubayashi M.   +13 more
europepmc   +1 more source

Well‐Defined Nickel Precatalysts: Form, Function, and Application

Chemistry – A European Journal, EarlyView.
This review provides guidance on which nickel precatalysts to choose for a given application or which properties to prioritize in reaction development. A summary of the ease of synthesis, stability, diversity, accessibility, modularity, and general applicability is provided along with a related infographic.
Morgan E. John, George A. Koutsantonis, Reto Dorta, Scott G. Stewart   +3 more
wiley   +1 more source

An anionic nickel-aluminium dihydride complex exhibiting cooperative catalytic behaviour. [PDF]

Chem Sci
Bienenmann RLM, Vedani L, Borys AM, Klein W, Hevia E.   +4 more
europepmc   +1 more source

N‐Sulfonyl Azalevoglucosan: A Versatile Platform for the Synthesis of Polysubstituted Piperidines

Chemistry – A European Journal, EarlyView.
Gain by strain: The synthesis of a levoglucosan analog, in which the pyranose oxygen has been replaced by a nitrogen, allows navigation on the piperidine ring to iteratively install functional groups at C1, C2, C3, C4, and C6 positions using simple experimental protocols with minimal protecting group manipulation.
Dylan Yorga, Jérôme Marrot, Ana Poveda, Nicolas Auberger, Jesús Jiménez‐Barbero, Jérôme Désiré, Yves Blériot   +6 more
wiley   +1 more source

Complexes of Zinc(II) Chloride with <i>N</i>-Vinyl-, <i>N</i>-Allyl- and <i>N</i>-Propargylimidazoles: Structural, Theoretical and Biological Studies. [PDF]

Pharmaceuticals (Basel)
Tyurin VS, Babasieva VS, Grigoriev MS, Parshina LN, Zamilatskov IA, Smolyarchuk EA, Nesterova OV, Turenko VN, Kolyganova TI, Arzumanian VG, Mutig K, Samsonov MY, Lebedeva SA.   +12 more
europepmc   +1 more source

Enabling Cross‐Coupling Reactivity of α‐Pentafluorosulfanyl Compounds with a Thermally Stable Organozinc α‐SF5 Reagent

Chemistry – A European Journal, EarlyView.
This work describes the first example of a thermally stable α‐SF5 organometallic reagent, which allows for extensive downstream functionalization by allylation and acylation reactions under copper catalysis, as well as palladium‐catalyzed Negishi‐type cross‐coupling conditions up to 96% yield. In silico analysis shines initial light on the requirements
Lujie Xu, David Rombach
wiley   +1 more source

Recent Advances in Dual Palladium Photoredox Catalysis. [PDF]

Chem Asian J
Vispute S, Patel A, Mokariya M, Dave S, Dhaduk Y, Pethani M, Davanagere PM, Padala K, Naveen T.   +8 more
europepmc   +1 more source

Self‐Immolative Poly(Benzyl Ether)s: Design Principles and Controlled Depolymerization

Chemistry – A European Journal, EarlyView.
Unzipping to Sustainability: This Concept article explores the thermodynamic design of quinone‐methide (QM)‐based poly(benzyl ether)s (PBEs). It explains how a low ceiling temperature (Tc), QM stability, and an entropic gain drive rapid depolymerization (“unzipping”) of PBEs into monomers.
Ji Woo Kim, Yewon Kang, Hyungwoo Kim
wiley   +1 more source

Modular synthesis of functionalized azetidines through visible-light copper-catalyzed carboamination of 1,3-dienes with azabicyclo[1.1.0]butanes. [PDF]

Chem Sci
Koo Y, Lee D, Park J, Hong S.
europepmc   +1 more source