Chemistry – A European Journal, EarlyView.Manganese oxides (MnOX) of different structures and with different Mn oxidation states exhibit significant variation in their reactivity toward the oxidation of allylic alcohols. Using two allylic alcohol model substrates, we demonstrate the relationship between activity and MnOX structure, Mn4+ content and incorporated secondary cations.
Erdogan Kasisari +6 more
wiley +1 more source
Effect of salicylic acid and silicon on physiological parameters and anatomical index of Scrophularia striata L. under drought stress. [PDF]
Sci RepShohani F +3 more
europepmc +1 more source
Chemistry – A European Journal, EarlyView.Cyclopropylamines have emerged as powerful photocatalytic building blocks. Upon light‐induced single‐electron oxidation, they undergo strain‐release ring opening to generate distonic iminium radicals that enable diverse transformations, including ring‐opening functionalization, formal [3 + 2] cycloadditions, radical cascades, and asymmetric bond ...
Maria Chiara Cabua +3 more
wiley +1 more source
Ligand-enabled distal desaturative lactonization of aliphatic acids. [PDF]
NaturePal T +5 more
europepmc +1 more source
Syntheses and Properties of Pentafluoroethylplumbanes in the Oxidation States +II, +III, and +IV
Chemistry – A European Journal, EarlyView.Syntheses of pentafluoroethyl substituted plumbanes in the formal oxidation states +II, +III, and +IV are reported. The compounds were characterized by multinuclear NMR spectroscopy, including 207Pb NMR spectroscopy, mass spectrometry and single‐crystal x‐ray diffraction experiments. ABSTRACT Mono‐, bis‐, and tris(pentafluoroethyl)plumbanes of the type
Michael Grasse +4 more
wiley +1 more source
Protective Effects of Allicin and Garlic-Derived Interventions Against Metabolic Dysfunction-Associated Steatotic Liver Disease: Current Evidence and Mechanistic Insights. [PDF]
NutrientsSun N +10 more
europepmc +1 more source
Chemistry – A European Journal, EarlyView.Charge and orbital control represent fundamental principles in organic chemistry. In this study, these principles are applied to the aldol reactions of a cyclic Ge‐dienolate. By systematically tuning the charge and orbital distributions of the Ge‐dienolates and their aldehyde reaction partners, regio‐ and stereoselective access to three distinct aldol ...
Taishi Nojima +2 more
wiley +1 more source
Practical Ni-Catalyzed Synthesis of Allylic Boronates. [PDF]
ACS OmegaRafetzeder EM +3 more
europepmc +1 more source
The Mechanism of Visible‐Light Photochemical Rearrangements of Conjugated Amide Enolates
Chemistry – A European Journal, EarlyView.Visible light irradiation of extended enolates of N‐benzylamides leads to homolytic C─N Bond cleavage, generating a biradical. Computational and mechanistic studies suggest rapid radical recombination within a solvent cage to give either ring‐expanded or rearranged products. ABSTRACT Deprotonation of conjugated amides forms colored solutions of lithium
James Mortimer +3 more
wiley +1 more source
Deciphering the nematicidal potential of plant-origin bioactive compounds against root-knot nematode, Meloidogyne incognita, through toxicity and molecular approaches. [PDF]
Pest Manag SciKamaraj N +5 more
europepmc +1 more source