Results 141 to 150 of about 62,639 (299)

Kinetics of the reactions of the p-methoxy-substituted benzhydryl cation with various alkenes and 1,3-dienes [PDF]

, 1990
Irrgang, Bernhard, Mayr, Herbert, Schade, Christian, Schneider, Reinhard   +3 more
core   +1 more source

Expanded Scorpionate and Siderophore‐Inspired Ligands: From Foundational Designs to Modern Applications

European Journal of Inorganic Chemistry, EarlyView.
The concept of scorpionate ligands has evolved significantly since the introduction of tris(pyrazolyl)borate. By integrating a biological supramolecular ligand scaffold with the classic scorpionate architecture, researchers have made notable strides in mimicking the active sites of nitrogenase and advancing homogeneous catalysis.
Austin Winfield Medley, Trandon Allen Bender   +1 more
wiley   +1 more source

Three reversibly interconvertible redox states of boradigermaallyl: syntheses of radical allyl anion and allyl dianion. [PDF]

Chem Sci
Miehe SF, Eichele K, Schubert H, Bettinger HF, Sindlinger CP, Wesemann L.   +5 more
europepmc   +1 more source

Correlation Between the Molecular Structure of Metal‐Supporting Ligands and Catalysis in the Oxygenase‐Mimicking Immobilized Metal Complex Catalysts

European Journal of Inorganic Chemistry, EarlyView.
The correlation between the structures of metal complexes immobilized in the mesopores of hydrophobically modified silicate supports was examined in relation to the catalytic activities toward C‐H oxidation. On the alkene oxidation with H2O2, the iron catalyst bearing bis(imidazolyl)methane ligand promotes allylic oxidation, whereas the mononuclear ...
Yuta Akizawa, Hiroe Fukuzaki, Nana Aizawa, Sho Ikeda, Airi Kawabe, Saori Nishiyama, Iori Nagasawa, Masaya Okamura, Shiro Hikichi   +8 more
wiley   +1 more source

Semi-Reduction of Allenes to Access Deuterated Allylic Isotopomers, Isotopologs and Enantioisotopomers. [PDF]

Angew Chem Int Ed Engl
Qi L, Thorat RA, Maxwell BD, Gladding JA, Arzola AJR, Sancheti SP, Sonstrom RE, Tang X, Anderson IJ, Pate BH, Clark JR.   +10 more
europepmc   +1 more source

Push–Pull Ynamines and Push–Pull Ynamides: Synthesis, Structure, Reactivity, and Application

European Journal of Organic Chemistry, EarlyView.
Push–pull ynamines and push–pull ynamides, which carry an EWG and an amino or amido group as EDG, are highly interesting classes of EDG‐EWG alkynes that have been intensively studied due to their exceptional reactivity. In this review, the synthesis, structure, reactivity, and application of push–pull ynamines, push–pull ynecarbamates, push–pull ...
Hans‐Joachim Gais
wiley   +1 more source

Synthesis of Insect Sex Pheromones by Ligand-Free Iron-Catalyzed Alkyl-Allyl Cross-Coupling Involving α,ω-Difunctionalized Aliphatic Grignard Nucleophiles and Allyl Electrophiles. [PDF]

ACS Omega
Tintar A, Guerret O, Liautard V, Gayon E, Lefèvre G.   +4 more
europepmc   +1 more source

The [3 + 2]- and [5 + 2]-cycloadditions of the cyclohepta-2,4-dienyl cation [PDF]

, 1987
Heilmann, Werner, Koschinsky, Rainer, Mayr, Herbert   +2 more
core   +1 more source

1,1‐Disubstituted Vinylbromides: Versatile Building Blocks for the Synthesis of Nitrogen‐Containing Heterocycles

European Journal of Organic Chemistry, EarlyView.
1,1‐Disubstituted vinylbromides are key intermediates for constructing nitrogen‐containing heterocycles. This review provides an overview of the synthetic applications of 1,1‐disubstituted vinylbromides and summarizes recent developments in reaction methodologies, mechanistic insights, and the structural diversity of N‐heterocyclic compounds accessible
Anne Westermeyer, Jun Fang, Chonghuo Liu, Guillaume Lefèvre, Gérard Guillamot, Phannarath Phansavath, Virginie Ratovelomanana‐Vidal   +6 more
wiley   +1 more source

Sterically Stabilized Homoleptic Copper and Gold Allyl Complexes. [PDF]

Organometallics
Button-Jennings D, Schley ND, Hanusa TP.
europepmc   +1 more source