Results 41 to 50 of about 62,031 (280)

The fluorine-NHC gauche effect: a structural and computational study [PDF]

open access: yes, 2013
Herein, we report the synthesis and X-ray structural analysis of a collection of fluorinated metal N-heterocyclic carbenes (Ag, Au, Pd, Rh, Ir) and their precursor salts.
Gilmour, R.   +4 more
core   +1 more source

Asymmetric preparation of antifungal 1-(4 -chlorophenyl)-1-cyclopropyl methanol and 1-(4 -chlorophenyl)-2-phenylethanol. Study of the detoxification mechanism by Botrytis cinerea [PDF]

open access: yes, 2011
Chiral alcohols are important as bioactive compounds or as precursors to such molecules. On the basis of the different antifungal properties of the enantiopure alcohol derivatives of 4-chlorophenyl cyclopropyl ketone and benzyl 4-chlorophenyl ketone ...
Aleu Casatejada, Josefina   +4 more
core   +2 more sources

Allylation of Aldiminomercaptotriazinones Using Allyl Halides and Allylmetal Compounds.

open access: yesChemInform, 2003
AbstractFor Abstract see ChemInform Abstract in Full Text.
openaire   +1 more source

Tailoring the Properties of Functional Materials With N‐Oxides

open access: yesAdvanced Functional Materials, EarlyView.
The properties of materials bearing N‐oxide groups are often dominated by the polar N+─O− bond. It provides hydrophilicity, selective ion‐binding, electric conductivity, or antifouling properties. Many of the underlying mechanisms have only recently been discovered, and the interest in N‐oxide materials is rapidly growing.
Timo Friedrich   +5 more
wiley   +1 more source

Designing Thermally Compatible Template‐Coating Pairs Toward Dimensionally Stable 3D Porous Carbons with Tunable Density

open access: yesAdvanced Functional Materials, EarlyView.
3D porous carbons with tunable density are crucial for energy storage, separations, and load‐bearing applications; however, their fabrication is often constrained by shrinkage during pyrolysis. This study optimizes and demonstrates the versatility of a template–coating pair strategy, producing materials that largely retain their shape and hierarchical ...
Adarsh Suresh   +7 more
wiley   +1 more source

Analysis of the Difference of Volatile Substances in Sprouted Garlic Based on Electronic Nose and GC-MS

open access: yesShipin gongye ke-ji
In order to investigate the differences of volatile compounds in sprouted garlic, an electronic nose and trap headspace-gas chromatography-mass spectrometry (HS-Trap-GC-MS) combined with orthogonal partial least squares discriminant analysis (OPLS-DA ...
Ying HAN   +7 more
doaj   +1 more source

Rich methane laminar flames doped with light unsaturated hydrocarbons. Part II: 1,3butadiene [PDF]

open access: yes, 2007
In line with the study presented in the part I of this paper, the structure of a laminar rich premixed methane flame doped with 1,3-butadiene has been investigated.
Allara   +47 more
core   +5 more sources

Ruthenium‐Catalyzed Allylation of Aromatic Compounds and Allylic Ether Formation. [PDF]

open access: yesChemInform, 2005
AbstractFor Abstract see ChemInform Abstract in Full Text.
Gen Onodera   +5 more
openaire   +1 more source

Multi‐Faceted Binder Enhancement via Slurry‐Applicable Thiol‐Ene Click Chemistry for Low‐Pressure‐Operable All‐Solid‐State Batteries

open access: yesAdvanced Functional Materials, EarlyView.
Cross‐linked binders with enhanced resiliencies under low operating pressures are designed via in situ thiol‐ene click reactions within slurries. Cross‐linking improves the Young's moduli and elasticities of the styrene‐butadiene rubber binders, effectively mitigating interparticle delamination within the composite cathodes induced by volumetric ...
Young Joon Park   +9 more
wiley   +1 more source

Enantioselective synthesis of (+)-petromyroxol, enabled by rhodium-catalyzed denitrogenation and rearrangement of a 1-sulfonyl-1,2,3-triazole [PDF]

open access: yes, 2015
Petromyroxol is a non-racemic mixture of enantiomeric oxylipids isolated from water conditioned with larval sea lamprey. The (+)-antipode exhibits interesting biological properties but only 1 mg was isolated from >100000 L of water.
Boyer, Alistair
core   +2 more sources

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