Allyl sulfur compounds and cellular detoxification system: effects and perspectives in cancer therapy [PDF]
, 2011 Natural organosulfur compounds (OSCs) have been shown to have chemopreventive effects and to suppress the proliferation of tumor cells in vitro through the induction of apoptosis.
Melino, S +4 more
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Dual Nickel/Photoredox‐Catalyzed Regio‐ and Enantioselective Alkenylation of Epoxides
Advanced Science, EarlyView.Ni/photoredox‐catalyzed stereoconvergent cross‐electrophile coupling of racemic epoxides with alkenyl bromides is described, affording β‐alkenyl products with up to 95% ee, excellent E‐selectivity, and complete regiocontrol. These versatile intermediates enable diverse chiral synthons; mechanistic studies suggest a halide ring‐opening followed by ...
Hongyan Lan +4 more
wiley +1 more source
Backbone Steric Constraints Underlie High Passive Membrane Permeability of N‐Alkyl Peptides
Angewandte Chemie, EarlyView.Beyond amide hydrogen removal, steric constraints encoded in N/Cα‐dually substituted backbones are uncovered as a key determinant of passive membrane permeability in N‐alkyl peptides. These constraints restrict conformational freedom and sterically limit backbone hydration during membrane permeation.
Ayumi Inayoshi +8 more
wiley +2 more sources
Comparative Insights and Overlooked Factors of Interphase Chemistry in Alkali Metal‐Ion Batteries
Advanced Energy Materials, EarlyView.This review presents a comparative analysis of Li‐, Na‐, and K‐ion batteries, focusing on the critical role of electrode–electrolyte interphases. It especially highlights overlooked aspects such as SEI/CEI misconceptions, binder effects, and self‐discharge relevance, emphasizing the limitations of current understanding and offering strategies for ...
Changhee Lee +3 more
wiley +1 more source
Angewandte Chemie, EarlyView.Cationic titanium sandwich catalysts display exceptional activity in the hydrodefluorination of Csp3─F bonds, in the presence of silanes and aromatic solvents (turnover numbers up to 3000). As a result, they can be used to defluorinate challenging fluoropolymers, such as poly(vinyl fluoride) (PVF) or poly(vinylidene fluoride) (PVDF).
Louis Le Moigne +9 more
wiley +2 more sources
Allium discoloration: the nature of onion pinking and garlic greening
Czech Journal of Food Sciences, 2004 Precursors involved in the formation of pink and green-blue pigments during onion and garlic processing, respectively, have been studied. It has been confirmed that the formation of both pigments is of a very similar nature, with (E)-S-(1-propenyl ...
R. Kubec +3 more
doaj +1 more source
Anti-wrinkle and anti-inflammatory effects of active garlic components and the inhibition of MMPs via NF-κB signaling. [PDF]
PLoS ONE, 2013 Skin aging is a multisystem degenerative process caused by several factors, such as, UV irradiation, stress, and smoke. Furthermore, wrinkle formation is a striking feature of photoaging and is associated with oxidative stress and inflammatory response ...
So Ra Kim +13 more
doaj +1 more source
A Tert‐Alkyl Terephthalate Derivative as a Universal Degradable Unit for Condensation Polymers
Angewandte Chemie, EarlyView.A sterically bulky dicarboxylic acid core bearing a tertiary alkyl ester enables photocatalytic C─O bond cleavage via generation of a stabilized tertiary alkyl radical. Incorporated into polyarylate, polyurethane, and polyester, this universal trigger facilitates efficient degradation under identical conditions (up to 99% within 2–4 h). Remarkably, the
Yasuyuki Nitta +7 more
wiley +2 more sources
Synthesis, Antibacterial and Antifungal Activity of 4-Substituted-5-Aryl-1,2,4-Triazoles
Molecules, 2001 A few 4-allyl/amino-5-aryl-1,2,4-triazoles were synthesized and tested for antibacterial and antifungal effects against Escherichia coli, Bacillus subtilis, Salmonella enteritidis, Staphylococcus aureus, Aspergillus niger and Candida albicans.
Aleksandra Buzarovska +4 more
doaj +1 more source
Nova metodologia de bromação dos adutos de morita-baylishillman E sua utilização como intermediários sintéticos na Preparação de heterociclos [PDF]
, 2008 TCC (graduação) - Universidade Federal de Santa Catarina. Centro de Ciências Físicas e Matemáticas. Curso de Química.Neste trabalho será apresentada uma nova metodologia sintética simples e eficiente para a preparação de (Z)-2-(bromometil)-2-alcenoatos a
FERREIRA, Misael
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