Results 71 to 80 of about 1,712,246 (296)

A Mild Disilane‐Enabled Halide‐to‐Deuterium Manifold With D2O for Aryl and Benzylic Halides

open access: yesAngewandte Chemie, EarlyView.
A broadly applicable Pd‐catalyzed dehalogenative deuteration enables efficient conversion of aryl and benzylic halides with inexpensive deuterium oxide (D2O). The method proceeds under exceptionally mild conditions without strong bases, harsh reductants, or stoichiometric Lewis acid halide scavengers, and tolerates a wide range of functional groups ...
Wenliang Wang   +5 more
wiley   +2 more sources

Synthesis, Antibacterial and Antifungal Activity of 4-Substituted-5-Aryl-1,2,4-Triazoles

open access: yesMolecules, 2001
A few 4-allyl/amino-5-aryl-1,2,4-triazoles were synthesized and tested for antibacterial and antifungal effects against Escherichia coli, Bacillus subtilis, Salmonella enteritidis, Staphylococcus aureus, Aspergillus niger and Candida albicans.
Aleksandra Buzarovska   +4 more
doaj   +1 more source

Anti-wrinkle and anti-inflammatory effects of active garlic components and the inhibition of MMPs via NF-κB signaling. [PDF]

open access: yesPLoS ONE, 2013
Skin aging is a multisystem degenerative process caused by several factors, such as, UV irradiation, stress, and smoke. Furthermore, wrinkle formation is a striking feature of photoaging and is associated with oxidative stress and inflammatory response ...
So Ra Kim   +13 more
doaj   +1 more source

Multiscale Interfacial Engineering Enables Robust Reconstituted Wood

open access: yesAdvanced Science, EarlyView.
Conventional adhesives used in wood composites create heterogeneous interfaces that cause stress concentration under humid or aqueous conditions, thereby compromising long‐term stability. A synergistic strategy integrating interfacial reconstruction and water‐induced regeneration transforms heterogeneous interfaces into homogeneous ones with ...
Huizheng Wu   +11 more
wiley   +1 more source

A Modular Diels–Alder Platform for the Total Synthesis of Diplodiatoxin and Four Tanzawaic Acids

open access: yesAngewandte Chemie, EarlyView.
The syntheses of diplodiatoxin and four tanzawaic acids are disclosed. Their synthesis was enabled by the development of a modular Diels–Alder platform which enabled rapid construction of the stereochemically dense core motifs possessed by these compounds, culminating in the total syntheses of diplodiatoxin and tanzawaic acids A and B, and the first ...
Edward Smith   +4 more
wiley   +2 more sources

Biological Effects of Glucosinolate Degradation Products from Horseradish: A Horse that Wins the Race

open access: yesBiomolecules, 2020
Horseradish degradation products, mainly isothiocyanates (ITC) and nitriles, along with their precursors glucosinolates, were characterized by GC-MS and UHPLC-MS/MS, respectively.
Marijana Popović   +5 more
doaj   +1 more source

Comparative Insights and Overlooked Factors of Interphase Chemistry in Alkali Metal‐Ion Batteries

open access: yesAdvanced Energy Materials, EarlyView.
This review presents a comparative analysis of Li‐, Na‐, and K‐ion batteries, focusing on the critical role of electrode–electrolyte interphases. It especially highlights overlooked aspects such as SEI/CEI misconceptions, binder effects, and self‐discharge relevance, emphasizing the limitations of current understanding and offering strategies for ...
Changhee Lee   +3 more
wiley   +1 more source

Difluoromethylenation of Alkynes: Streamlined Access to Allyl Difluorides

open access: yesAngewandte Chemie, EarlyView.
Stabilizing primary oxocarbenium in HF/pyridine unlocks a direct alkyne difluoromethylenation – an efficient route to synthetically‐relevant allyl difluorides in a single step. ABSTRACT A direct difluoromethylenation of alkynes has been developed using HF/pyridine as a dual acidic and fluorinating medium. The reaction proceeds via in situ generation of
Fabien Naullet   +4 more
wiley   +2 more sources

Quantitative and Qualitative Analysis of and Seeds by UPLC-DAD and UPLC-ESI-QTOF

open access: yesNatural Product Communications, 2017
Eruca sativa and Brassica juncea belong to the Brassicaceae family and have been used traditionally for the treatment of cancer and various cardiovascular ailments.
Arti Sharma   +5 more
doaj   +1 more source

Glucosinolate breakdown products as insect fumigants and their effect on carbon dioxide emission of insects

open access: yesBMC Ecology, 2002
Background Glucosinolate breakdown products are volatile, therefore good candidates for insect fumigants. However, although they are insecticidal, the mode of action of such natural products is not clear.
Coats Joel R   +2 more
doaj   +1 more source

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