Results 41 to 50 of about 470,592 (137)

[2,3]-Wittig rearrangements of (trimethylsilyl)methyl allyl ethers

, 1996
A Wittig-Still type [2,3]-sigmatropic rearrangement of (trimethylsilyl)methyl allyl ethers has been ...
Mulzer, J., List, B.
core   +1 more source

Methyl/Allyl Monolayer on Silicon: Efficient Surface Passivation for Silicon-Conjugated Polymer Hybrid Solar Cell

, 2016
We demonstrate a hybrid Schottky junction solar cell based on methyl/allyl groups terminated silicon nanowire arrays (SiNWs) and poly­(3,4-ethylenedioxythiophene)/poly­(styrenesulfonate) with a power conversion efficiency (PCE) of 10.2%.
Tao Song (130854), Yunfang Zhang (585611), Huaixin Wei (1682008), Baoquan Sun (1331757), Fute Zhang (1948225), Dong Liu (115204)   +5 more
core   +1 more source

Alkoxyallenes in Modern Synthesis: Reactivity, Catalysis, and Complexity Generation

Advanced Synthesis &Catalysis, Volume 368, Issue 17, 1 September 2026.
The last decade has witnessed a remarkable transformation in alkoxyallene chemistry. Although historically employed as synthetic equivalents of acrolein or as versatile 3C synthons, alkoxyallenes are now increasingly recognized as highly adaptable platforms for synthetic design.
A. Lanfranco, M. Rusconi, J. Saglietto, P. Renzi, A. Deagostino, E. Azzi   +5 more
wiley   +1 more source

Supplementary Material for: Methyl Sulfone Manifests Anticancer Activity in a Metastatic Murine Breast Cancer Cell Line and in Human Breast Cancer Tissue - Part 2: Human Breast Cancer Tissue

, 2017
Background: Methyl sulfone is a small molecule that reverses cancerous phenotypes of a melanoma cell line. Here, we sought to determine whether methyl sulfone was effective against human breast cancer tissue.
Bannon M. (4139335), Caron J.M. (4139332), Deckers P.J. (4139344), Monteagudo L. (4139338), Sanders M. (4139341)   +4 more
core   +1 more source

1,3‐Dipolar Cycloaddition of Nitroalkanes as a Tool of DOS/LOS‐Like Strategy for the Synthesis of Isoxazoles and Isoxazolines

ChemistryEurope, Volume 4, Issue 9, September 2026.
A broadly applicable synthetic platform based on a DOS/LOS‐like strategy is implemented for the case of sp3‐enriched isoxazole/isoxazoline building blocks. The method is based on a [3+2] cycloaddition of nitroalkanes and various alkenes or alkynes. The utility of the proposed approach is illustrated by the discovery of JAK2‐selective inhibitors.
Bohdan A. Chalyk, Kostiantyn O. Halos, Anastasiia Grynyova, Bohdan S. Sosunovych, Bohdan V. Vashchenko, Oleksandr Zginnyk, Anna Beshtynarska, Nataliia Shliakhtova, Petro Borysko, Angelina V. Biitseva, Konstantin S. Gavrilenko, Dmytro M. Volochnyuk, Oleksandr O. Grygorenko   +12 more
wiley   +1 more source

Theoretical study on the elimination kinetics in the gas phase of allyl methyl compounds

, 2018
The thermal decomposition kinetics of allyl methyl amine, allyl methyl ether, and allyl methyl sulfide in the gas phase has been studied theoretically using the M06-2x/aug-cc-pVTZ quantum chemical approach.
Zahedi, Ehsan, SHIROUDI, Abolfazl, Oliaey, Ahmad Reza, DELEUZE, Michael   +3 more
core   +1 more source

Relay Approach: A Convergent Synthesis of Key Fragments en route to (+)‐Neosorangicin A

Chemistry – A European Journal, Volume 32, Issue 32, 24 August 2026.
A selective synthesis of three key fragments of the antibiotically active (+)‐neosorangicin A is reported, providing a foundation for its convergent total synthesis and proof of strategy via a relay approach. ABSTRACT Herein, we report the synthesis of the three key fragments of the macrolide antibiotic (+)‐neosorangicin A, a compound exhibiting potent
Marvin Wenninger, Maxim Munt, Le Chang, Rositsa Stoykova, Roberto Ojcius, Oliver Spieß, Dieter Schinzer   +6 more
wiley   +1 more source

Structure of Eugenol (4-Allyl-2-methoxyphenol)

, 2016
Structure of Eugenol (4-Allyl-2-methoxyphenol)
Garima Chouhan (682422), Hani A. Ozbak (3238965), Mohammad Islamuddin (682421), Hassan A. Hemeg (3238962), Muzamil Yaqub Want (3238968), Farhat Afrin (278211)   +5 more
core   +1 more source

Retro‐Hetero‐Michael Addition Strategies in Organic Synthesis

European Journal of Organic Chemistry, Volume 29, Issue 32, 24 August 2026.
In this review, synthetic approaches to carbo‐ and heterocyclic compounds, including natural products, published in the last 15 years (2011–2025) which have either relied upon or included a retro‐hetero‐Michael addition step at any stage are discussed.
Dina Scarpi, Ernesto G. Occhiato
wiley   +1 more source

Palladium‐Catalyzed Alkynylation of Allylic Carbonates With Terminal Alkynes: Stereoretentive Access to 1,4‐Enynes and Diarylalkenyl Propargylic Frameworks

Advanced Synthesis &Catalysis, Volume 368, Issue 16, 18 August 2026.
A palladium‐catalyzed alkynylation of cinnamyl carbonates with terminal alkynes provides efficient and stereoretentive access to 1,4‐enynes, enabling the synthesis of challenging diarylalkenyl propargylic frameworks. A mild and efficient palladium‐catalyzed alkynylation of 3‐aryl, 3,3‐diaryl, and aliphatic allylic carbonates with terminal alkynes has ...
Yuri Gazzilli, Antonella Goggiamani, Federico Marrone, Francesco Stipa, Ilaria Ambrogio, Alessandro Carlone, Giancarlo Fabrizi, Antonia Iazzetti   +7 more
wiley   +1 more source