Paired electrocatalysis unlocks cross-dehydrogenative coupling of C(sp3)-H bonds using a pentacoordinated cobalt-salen catalyst. [PDF]
Liu K +7 more
europepmc +1 more source
Sweeteners in E-Cigarettes: A Minireview of Flavoring and Biological Action. [PDF]
Tkach VV +6 more
europepmc +1 more source
Ion-Pair Hydrogen Atom Transfer Catalysis Enables Cr-Catalyzed Allylation of Ketones Using Hydrocarbon Alkenes. [PDF]
Arii S +4 more
europepmc +1 more source
A fragment based approach towards curating, comparing and developing machine learning models applied in photochemistry. [PDF]
Pérez-Soto R +8 more
europepmc +1 more source
β-Asarone Attenuates Neuroinflammation of Alzheimer's Disease by Activating Autophagy and Suppressing NLRP3 Inflammasome Assembly. [PDF]
Xu Z +6 more
europepmc +1 more source
Related searches:
We report here a deallylative β-acylalkylation reaction of allylbenzene derivatives with allyl alcohols in the presence of Cp*Rh catalysts. Allylbenzenes possessing pyridyl and pyrazolyl directing groups were converted to β-aryl ketones via the cleavage of C(aryl)-C(allyl) bonds.
Soya Ishikawa +5 more
openaire +2 more sources
Rhodium-diphosphite catalysed hydroformylation of allylbenzene and propenylbenzene derivatives
Inorganica Chimica Acta, 2006The asymmetric hydroformylation of allylbenzenes and propenylbenzenes is an important tool for obtaining high value intermediates for the pharmaceutical and perfume industry. We have studied these reactions with rhodium-chiral diphosphite systems. The diphosphite ligands 6 and 7 with carbohydrate backbone have high regioselectivities in trans-anethole ...
Axet, M. Rosa +2 more
openaire +1 more source
Synthesis of Allylbenzene Derivatives through sp3 C–H Bond Functionalization of Toluene Derivatives
Synlett, 2017An sp3 C–H bond-transformation reaction of toluene substrates to afford the corresponding allylbenzene derivatives is described. Optimum conditions were identified as involving the use of tetrabutylammonium iodide and tert-butyl hydroperoxide at 80 °C.
Majid Ghazanfarpour-Darjani +4 more
openaire +1 more source
Regioselective Cp*Ir(III)-Catalyzed Allylic C–H Sulfamidation of Allylbenzene Derivatives
The Journal of Organic Chemistry, 2019In this study we report the development of the regioselective Cp*Ir(III)-catalyzed allylic C-H sulfamidation of allylbenzene derivatives, using azides as the nitrogen source. The reaction putatively proceeds through a Cp*Ir(III)-π-allyl intermediate and demonstrates exclusive regioselectivity for the branched position of the π-allyl.
Amaan M. Kazerouni +4 more
openaire +2 more sources

