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C3-Chiral Tripodal Amido Complexes
Chemistry - A European Journal, 2001A comprehensive study into the coordination chemistry of two C3-chiral tripodal amido ligands has been carried out. The amido ligands contain a trisilylmethane backbone and chiral peripheral substituents. The amine precursors. HC(SiMe2NH[(S)-1-phenylethyl]]3 (1) and HC[SiMe2NH[(R)-1-indanyl]]3 (2) were found to be in equilibrium in solution with the ...
L H, Gade +8 more
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Organometallics, 2008
The solution and solid-state characterization of the tetraorganozincates [(TMEDA)2Li2ZnMe(NMe2)3] (2) and [(TMEDA)2Li2ZnMe4] (4) and the all-amido triorganozincate [{(TMEDA)LiZn(NMe2)3}2] (3) are reported. X-ray crystallographic studies reveal that 2 and 4 exhibit similar structural motifs, namely trinuclear Li···Zn···Li chain arrangements held ...
Armstrong, D.R. +4 more
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The solution and solid-state characterization of the tetraorganozincates [(TMEDA)2Li2ZnMe(NMe2)3] (2) and [(TMEDA)2Li2ZnMe4] (4) and the all-amido triorganozincate [{(TMEDA)LiZn(NMe2)3}2] (3) are reported. X-ray crystallographic studies reveal that 2 and 4 exhibit similar structural motifs, namely trinuclear Li···Zn···Li chain arrangements held ...
Armstrong, D.R. +4 more
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Cyclooctatetraenyl calcium and strontium amido complexes
Dalton Transactions, 2018The first examples of Ca and Sr amido complexes built on a cyclooctatetraenyl platform are reported.
Farid M. Sroor +2 more
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Gallane Complexes with Amido−Amine Ligands
Inorganic Chemistry, 2000Gallane complexes bearing amido-amine ligands -N(R)CH2CMe2CH2NMe2 [R = H or SiMe3 (TMS)], (H2Ga[N(H)CH2CMe2CH2NMe2])2, 1, H2Ga[N(TMS)CH2CMe2CH2NMe2], 2, (H(Cl)Ga[N(H)CH2CMe2CH2NMe2])2, 3, ([(TMS)2N](H)Ga[N(H)CH2CMe2CH2NMe2])2, 4, and HGa[N(TMS)CH2CMe2CH2NMe2]2, 5, were synthesized from the reactions of the quinuclidine adducts of mono- and ...
B, Luo, M, Pink, W L, Gladfelter
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Inorganic Chemistry, 2000
This report describes the synthesis and characterization of a series of octaethylporphyrin derivatives in which the porphyrin pi-network is connected to phenyl, 3-fluoranthenyl, or 1-pyrenyl aromatic systems through a meso amino or amido nitrogen. Metal-free bases and zinc(II) and iron(III) complexes have been obtained.
K, Jayaraj +3 more
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This report describes the synthesis and characterization of a series of octaethylporphyrin derivatives in which the porphyrin pi-network is connected to phenyl, 3-fluoranthenyl, or 1-pyrenyl aromatic systems through a meso amino or amido nitrogen. Metal-free bases and zinc(II) and iron(III) complexes have been obtained.
K, Jayaraj +3 more
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Inorganic Chemistry, 2005
The insertion of carbodiimides into existing metal-heteroatom bonds is an important preparative route for the synthesis of useful ligand systems such as amidinates and guanidinates. Our interest lies in multiple insertions at one metal center and the mechanisms of insertion and rearrangement. We have synthesized and characterized [Me(2)NC(N(i)Pr)(2)](n)
Amanda P, Kenney +3 more
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The insertion of carbodiimides into existing metal-heteroatom bonds is an important preparative route for the synthesis of useful ligand systems such as amidinates and guanidinates. Our interest lies in multiple insertions at one metal center and the mechanisms of insertion and rearrangement. We have synthesized and characterized [Me(2)NC(N(i)Pr)(2)](n)
Amanda P, Kenney +3 more
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Syntheses of Amido-, Carbamido- and Carbamatoalkylnaphthols [PDF]
Csütörtöki, Renáta +2 more
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Stoichiometry of the amido black reaction with proteins
Analytical Biochemistry, 1973Abstract Amido black 10B (C 22 H 14 N 6 O 9 S 2 Na 2 ) reacted with nine different proteins to yield nearly identical molar ratios of sorbed dye to protein-bound basic amino acids.
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