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Fluorinated Aminophosphonates and Aminophosphonic Acids: A Journey through Recent Advances
European Journal of Organic ChemistryThis review aims to summarize the most recent developments in the chemistry of fluorinated aminophosphonates and aminophosphonic acids, with a particular focus on literature published since the turn of 2016/2017. Fluorinated derivatives of aminophosphonates and aminophosphonic acids represent a rapidly growing area of interest due to their unique ...
Tomasz Cytlak +2 more
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Aminophosphonate Corrosion Inhibitors for Steel
Protection of Metals, 2003The protective properties of aminophosphonic acids and their magnesium and calcium complexes were studied on the example of rotating steel cylinders specimens in soft water. Only two of the seven acids studied, namely 1,1-hydroxycarboxypropane-3-amino-di(methylenephosphonic) and hexamethylenediamine-N,N-tetra(methylenephosphonic) acids, can suppress ...
Yu. I. Kuznetsov +2 more
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Mécanismes de Formation d'α-Aminophosphonates
Phosphorus, Sulfur, and Silicon and the Related Elements, 2003When di-n-decylphosphonate 1a or di-benzylphosphite 1b are reacted with furan imine 2a or thiophenic imine 2b , the reaction leads to an f -aminophosphonate: 3a , 3b , or 3c following an ion- or radical-based reaction.
Adyl Oussaid +4 more
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Asymmetric Synthesis of Aminophosphonic Acids
Phosphorus, Sulfur, and Silicon and the Related Elements, 1999A new synthesis of chiral α- and β-aminophosphonic acids is described which involves a highly diastereoselective addition of phosphite and phosphonate anions to enantiopure sulfinimines.
Marian Miko Zajczyk +2 more
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An organocatalytic biomimetic approach to α-aminophosphonates
Chemical Communications, 2015A novel biomimetic approach to optically active α-aminophosphonates from readily available acylphosphonates employing chiral base catalysis.
Dorota, Kowalczyk, Łukasz, Albrecht
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Aminophosphonate Metal Complexes of Biomedical Potential
Current Medicinal Chemistry, 2013Metals and their complexes with organic ligands have an important role in biochemical systems such as enzymatic catalysis, metal ion transfer across the cell membranes, treatment of malignancy, rheumatoid arthritis, ulcer and other types of diseases. Special attention is directed to metal complexes with ligands which are important in biological systems,
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The Aza-α-aminophosphonate Macrocycle
Phosphorus, Sulfur, and Silicon and the Related Elements, 2009In order to combine the properties of aza-macrocycles and aminophosphonates, a new tetraaminophosponic macrocyclic molecule has been synthesized. This potential receptor for organic molecules as well as for metal cations was obtained by condensation, hydrophosphonylation, and deprotection. The second synthetic step was performed using di(trimethylsilyl)
Piotr Młynarz +3 more
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ChemInform Abstract: AMINOPHOSPHONATE‐AMIDOPHOSPHATE REARRANGEMENT
Chemischer Informationsdienst, 1978AbstractBenzalanilin (I) und das Natriumsalz (II) reagieren bei erhöhter Temperatur über die Phosphonatzwischenstufe (III) nach dem Ansäuem zu dem Amidophosphat (IV) oder bei Behandlung mit Iodmethan zu dem Amidophosphat (V).
A. N. PUDOVIK +3 more
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Tetrahedron Letters, 2017
Abstract A convenient synthetic approach towards previously unknown N- and N,O-silylated α-iminophosphonates bearing fluoroalkyl groups at the imine C atom was developed. The synthetic potential of the compounds was demonstrated by their easy functionalization and the straightforward preparation of biorelevant aminophosphonates and free ...
Yuliya V. Rassukana +3 more
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Abstract A convenient synthetic approach towards previously unknown N- and N,O-silylated α-iminophosphonates bearing fluoroalkyl groups at the imine C atom was developed. The synthetic potential of the compounds was demonstrated by their easy functionalization and the straightforward preparation of biorelevant aminophosphonates and free ...
Yuliya V. Rassukana +3 more
openaire +1 more source

