Solvent‐Free Thermal Defect Engineering in Molecular Frameworks With Volatile Linkers
Thermal removal of neutral volatile linkers enables precise and solvent‐free generation of metal vacancies in MOFs. This strategy affords redox‐stable, coordinatively unsaturated FeII sites with tunable spin, ligand coordination, and catalytic behavior. The approach offers a general route to design defect‐functional materials through local coordination
Sonia Martínez‐Giménez +9 more
wiley +1 more source
High-Temperature Stable Amorphous Al<sub>2-<i>x</i></sub>(ZrY)<sub><i>x</i></sub>O<sub>3</sub> Thin Film Insulators: An Alternative to Crystalline Alumina. [PDF]
Salvadores Farran N +11 more
europepmc +1 more source
Ball‐milling Cu‐based metallic glasses with ceria creates a unique nanostructure where metallic glass particles are wrapped by CeO2 nanoparticles. The intimate integration triggers copper state reorganization during reaction and aging, boosting CO oxidation and COPrOx activity.
Maahin Mirzay‐Shahim +17 more
wiley +1 more source
Allotrope-dependent physicochemical and optical properties of red and grey selenium nanoparticles. [PDF]
Ferroudj A, Csík A, Prokisch J.
europepmc +1 more source
Opportunities of Semiconducting Oxide Nanostructures as Advanced Luminescent Materials in Photonics
The review discusses the challenges of wide and ultrawide bandgap semiconducting oxides as a suitable material platform for photonics. They offer great versatility in terms of tuning microstructure, native defects, doping, anisotropy, and micro‐ and nano‐structuring. The review focuses on their light emission, light‐confinement in optical cavities, and
Ana Cremades +7 more
wiley +1 more source
Boron Nitride-Modified Hemp Nanofiber Reinforced Slag-Based Geopolymer Composites: Mechanical, Microstructural and Fire Resistance Performance. [PDF]
Filazi A +4 more
europepmc +1 more source
This study demonstrates a self‐assembly process to generate free‐standing piezoelectric nanomembranes, forming ultracompact microtubular acoustic wave sensors and actuators. The miniaturized 3D piezoelectric platform reported in this work can be applied in telecommunication, energy harvesting, and acoustofluidics. Moreover, the 3D self‐assembly can add
Raphaël C. L‐M. Doineau +9 more
wiley +1 more source
Electrostatic-confinement-induced regioselective C-H functionalization of polyolefins. [PDF]
Zhang M +8 more
europepmc +1 more source
In this work, low bandgap (≈1.55 eV) semitransparent perovskite solar cells (ST‐PSCs) having thin (thickness < ≈100 nm) perovskite layers and transparent conductive oxide‐based rear electrodes are fabricated using vacuum‐deposition methods. Two different ST‐PSCs demonstrated a high light utilization efficiency value of 4.2 (PCE: 9.26% and AVT: 45.3 ...
Abhyuday Paliwal +9 more
wiley +1 more source
How to Handle Hard-to-Purify Polymers: Ammonium Sulfate Precipitation of rPEG as a Prototype for Amorphous and Flexible Polymers. [PDF]
Simon L, Dreier P, Frey H.
europepmc +1 more source

