Results 201 to 210 of about 69,365 (292)

Effect of Acetaldehyde on P-Hydroxylation of Aniline by Aniline Hydroxylase

open access: yesJapanese Journal of Pharmacology, 1972
KINOSHITA, Go   +4 more
openaire   +2 more sources

Ni2‐Imido Bispincer Platforms: Cooperative Reactivity Enabled Through Substrate Addition Across a Ni2N Unit

open access: yesChemistry – A European Journal, EarlyView.
Ni2 bispincer complexes with an embedded central imido anchor are presented. The bispincer complexes leverage the high basicity of imido ligands to facilitate 1,2 addition of weak B─H and Si─H bonds, resulting in hydrido–amido complexes and resultingly a contortion of a Ni─Ni sigma bond to form an S = 1 species. The 1,2 addition is proposed to serve as
David de los Santos   +2 more
wiley   +1 more source

Cyclopropylamine‐Derived Distonic Iminium Radicals: Photoinduced Strategies in Chemo‐ and Stereo‐Selective Synthesis

open access: yesChemistry – A European Journal, EarlyView.
Cyclopropylamines have emerged as powerful photocatalytic building blocks. Upon light‐induced single‐electron oxidation, they undergo strain‐release ring opening to generate distonic iminium radicals that enable diverse transformations, including ring‐opening functionalization, formal [3 + 2] cycloadditions, radical cascades, and asymmetric bond ...
Maria Chiara Cabua   +3 more
wiley   +1 more source

Hybrid Macrocyclic Peptides — Synthetic Strategies to Diversify and Cyclize Peptide Libraries in Phage Display Selections

open access: yesChemistry – A European Journal, EarlyView.
Hybrid macrocyclic peptides unite genetically encoded peptide libraries with the structural complexity of synthetic small molecules. This Review critically analyzes phage‐compatible cyclization and diversification chemistries, highlights emerging opportunities beyond traditional cysteine‐based approaches, and outlines how future advances may enable the
Titia Rixt Oppewal, Clemens Mayer
wiley   +1 more source

Rhodium‐Catalyzed Synthesis of Enantioenriched α‐Substituted Primary Amines Through Asymmetric Transfer Hydrogenation

open access: yesChemistry – A European Journal, EarlyView.
Enantioenriched α‐substituted primary amines are efficiently prepared by rhodium‐catalyzed asymmetric transfer hydrogenation of ortho‐hydroxyaryl N─H imines under mild conditions using a low catalyst loading and ammonium formate as the hydrogen source in high yields (up to 99%) and enantioselectivities (up to 99% ee).
Chonghuo Liu   +4 more
wiley   +1 more source

Synthesis, biological evaluation, molecular docking, molecular dynamics simulation, and ADME studies of novel carbazole-aniline hybrids as cytotoxic agents. [PDF]

open access: yesBMC Chem
Moradimehrabadi M   +7 more
europepmc   +1 more source

Spatially Configuring RGO Interlayers With PANI/Lignin Nanoparticles Toward High‐Performance Asymmetric Supercapacitors

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
A novel PLNPs@RGO electrode, self‐assembled from polyaniline/lignin conjugated mesoporous nanoparticles (PLNPs) and reduced graphene oxide, exhibits excellent capacitance and high energy density in supercapacitors. The high‐performance flexible solid‐state asymmetric supercapacitor (FSAC) plays a critical role in advancing the innovation of next ...
Mengya Sun   +6 more
wiley   +1 more source

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