Radical Cascade Combining Cross‐Olefin Coupling with the Smiles‐Truce Rearrangement
Angewandte Chemie International Edition, EarlyView.We present a cobalt‐catalysed radical cascade that efficiently merges two alkene starting materials to form multiple bonds in a single step. The process begins with a cobalt‐catalysed hydrogen‐atom transfer‐to a styrene double bond, followed by a Giese addition.
Jingyang Qin +3 more
wiley +1 more source
Angewandte Chemie International Edition, EarlyView.This study presents the synthesis and binding properties of a new family of o‐terphenyl‐based macrocycles, TP[n] (n = 2‐8). The trimer variant efficiently binds phenylalanine in water with a 10‐fold selectivity compared to other amino acids and aromatic neurotransmitters.
Swapnil Ghule +5 more
wiley +1 more source
CXVII.—Aniline-black and allied compounds. Part II [PDF]
J. Chem. Soc., Trans., 1912 Arthur George Green +1 more
openaire +1 more source
Comparison between polymerized ionic liquids synthesized using chain-growth and step-growth mechanisms used as stationary phase in gas chromatography [PDF]
, 2016 David, Frank +2 more
core +1 more source
Substituted 1,1,1-triaryl 2,2,2-trifluoroethanes and processes for their synthesis [PDF]
Synthetic procedures to tetraalkyls, tetraacids, and dianhydrides substituted 1,1,1-triaryl 2,2,2-trifluoroethanes which comprises: (1) 1,1-bis(dialkylaryl) 1-aryl-2,2,2-trifluoroethane, (2) 1,1-bis(dicarboxyaryl) 1-aryl-2,2,2-trifluoroethane, or (3 ...
Alston, William B., Gratz, Roy F.
core +1 more source
Photoelectrocatalytic Cl-mediated C(sp 3)–H aminomethylation of hydrocarbons by BiVO4 photoanodes
Nature CommunicationsInterfacial photoelectrochemistry at photoanodes has been extensively researched for solar energy conversion, but its application for the production of high-value-added chemical compounds in organic chemistry still presents challenges.
Anzai Shi +3 more
doaj +1 more source
Antistaphylococcal Triazole-Based Molecular Hybrids: Design, Synthesis and Activity
PharmaceuticalsBackground: In the era of resistance, the design and search for new “small” molecules with a narrow spectrum of activity that target a protein or enzyme specific to a certain bacterium with high selectivity and minimal side effects remains an urgent ...
Kostiantyn Shabelnyk +10 more
doaj +1 more source
Site Alteration Effects from Rocket Exhaust Impingement During a Simulated Viking Mars Landing. Part 2: Chemical and Biological Site Alteration [PDF]
Chemical and biological alteration of a Mars landing site was investigated experimentally and analytically. The experimental testing was conducted using a specially designed multiple nozzle configuration consisting of 18 small bell nozzles.
Fennessey, P. V. +2 more
core +1 more source
Dynamic Covalent Radical Recombination for the Assembly of Tuneable Responsive Porous Organic Cages
Angewandte Chemie International Edition, EarlyView.Dynamic covalent chemistry (DCC) based on reversible radical recombination enables the assembly of responsive, C─C‐linked organic cages. Substituent‐controlled aryldicyanomethyl radicals form discrete, porous architectures with tuneable topology of Tri2 and Tri4 cages, gas selectivity, chromism, and self‐healing behaviour, establishing radical‐based ...
Yannic Hartmann +6 more
wiley +1 more source
Diversity of 3-chloroaniline and 3,4-dichloroaniline degrading bacteria isolated from three different soils and involvement of their plasmids in chloroaniline degradation. [PDF]
, 2002 CRUL, Katrien +7 more
core +2 more sources