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Applications of Supramolecular Anion Recognition [PDF]

open access: yesChemical Reviews, 2015
Philip A. Gale   +2 more
exaly   +4 more sources

Anion Recognition and Sensing: The State of the Art and Future Perspectives [PDF]

open access: yesAngewandte Chemie - International Edition, 2001
Anion recognition chemistry has grown from its beginnings in the late 1960s with positively charged ammonium cryptand receptors for halide binding to, at the end of the millennium, a plethora of charged and neutral, cyclic and acyclic, inorganic and ...
Philip A. Gale, Paul D Beer
exaly   +4 more sources
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Anion Recognition by Benzoxaborole

The Journal of Organic Chemistry, 2022
The binding types (H-bonding or coordinate) and stability constants for complexes of 11 mono- and di-anions with benzoxaborole (1) were determined by 1H and 11B NMR titrations in DMSO or MeCN. Compared to phenylboronic acid (PBA), 1 is a stronger Lewis acid and a poorer H-bond donor with only one B-OH group, which is expected therefore to recognize ...
Mayte A. Martínez-Aguirre   +3 more
openaire   +2 more sources

Anion recognition by silanetriol in acetonitrile

Organic & Biomolecular Chemistry, 2022
Anion recognition ability and organocatalytic activity of a silanetriol are firstly presented by comparing with those of a series of silanol derivatives.
Shin-ichi Kondo   +5 more
openaire   +2 more sources

A Hexapodal Capsule for the Recognition of Anions

Journal of the American Chemical Society, 2021
We herein describe the preparation, characterization, and recognition characteristics of novel hexapodal capsule 1 composed of two benzenes joined by six hydrogen bonding (HB) groups to encircle space. This barrel-shaped host was obtained by reversible imine condensation of hexakis-aldehyde 2 and hexakis-amine 3 in the presence of oxyanions or halides ...
Han Xie   +5 more
openaire   +2 more sources

Anion recognition by Thiostrepton

Bioorganic & Medicinal Chemistry Letters, 2001
A bicyclic polypeptide antibiotic thiostrepton forms both 1:1 and 1:2 complexes with anions (as tetrabutylammonium salts) in organic solvents with K2 >K1 for F- and K2Cl-, Br-, HSO4-, H2PO4-, but in CHCl3 they follow a different order: Cl- approximatelyHSO4- >F- approximately AcO- > Br > H2PO4-.
C, Godoy-Alcántar   +2 more
openaire   +2 more sources

Anion Recognition by Dimetallic Cryptates

open access: yesCoordination Chemistry Reviews, 2001
Bis-tren cryptands (i.e. octamine cages consisting of two tripodal tetramine subunits covalently linked by given spacers) are able to incorporate first two metal ions, then an ambidentate anion, according to a cascade mechanism.
Valeria Amendola   +2 more
exaly   +2 more sources

Shuttling Through Anion Recognition

Angewandte Chemie - International Edition, 2004
David Leigh
exaly   +3 more sources

Recognition and sensing of fluoride anion

Chemical Communications, 2009
Fluoride anion recognition is attracting a mounting interest in the scientific community due to its duplicitous nature. It is a useful chemical for many industrial applications, and it has been used in human diet, but, recently it has been accused for several human pathologies.
CAMETTI, MASSIMO, Kari Rissanen
openaire   +3 more sources

Indole as a scaffold for anion recognition

Organic & Biomolecular Chemistry, 2007
Indole has an acidic N-H that can be used to form hydrogen bonds to anions and in this paper the synthesis of three new suitably functionalised indole based anion receptors is presented along with their evaluation using (1)H NMR titration techniques.
Frederick M, Pfeffer   +2 more
openaire   +2 more sources

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