Results 1 to 10 of about 33,415 (172)

De Novo Design and Structural Optimization of Mn(salen)‐Based Artificial Metalloenzymes for Asymmetric Sulfoxidation

open access: yesAngewandte Chemie, EarlyView.
We report the computational design of de novo proteins that bind Mn(salen)‐based complexes (L1) using Rosetta FastDesign and verified by AlphaFold2. After screening, the catalytic activity for the promising design (dnMSBP) toward enantioselective sulfoxidation of thioanisole was optimized based on its crystal structure. With 10 different substrates, we
Jing‐Xiang Wang   +6 more
wiley   +2 more sources

Electrocatalytic CO2 Reduction over Sn‐Cu Bimetallic Catalysts Synthesized via an Amalgamated Lithium Metal Method

open access: yesAdvanced Science, EarlyView.
An amalgamated lithium metal method enables systematic control of Sn–Cu active‐site dimensions from isolated atoms to nanocrystallites. Increasing the metal loading shifts CO2 electroreduction selectivity from acetaldehyde on highly dispersed Sn–Cu sites to formate on Sn‐rich crystallites, revealing how bimetallic dispersion and local coordination ...
Minghao Xie   +6 more
wiley   +1 more source

Engineering Na‐Rich P2‐Type Layered Oxides Through Li/Ti Dual Doping for Oxygen Redox Activation and Superior Structural Stability

open access: yesAdvanced Energy Materials, EarlyView.
P2‐type sodium layered oxides have potential for high‐voltage operation but suffer from structural instability and capacity fading. This work demonstrates that synergistic Li and Ti co‐doping enhances sodium inventory, suppresses detrimental phase transitions, and activates reversible lattice oxygen redox.
Rishika Jakhar   +16 more
wiley   +1 more source

Electrolyte Interfacial Reactivity Regulates Alloying Anode Pulverization

open access: yesAdvanced Energy Materials, EarlyView.
Electrolyte interfacial reactivity governs the degradation of micrometer‐sized alloying anodes by dictating grain refinement and SEI growth. A high‐reactivity ester‐based electrolyte drives pulverization into fine nanoparticles encapsulated by a thick SEI, forming dense electrodes, whereas a low‐reactivity ether‐based electrolyte enables porous ...
Namhyung Kim   +21 more
wiley   +1 more source

Enhanced Structural Reversibility and Electrochemical Stability Via Fe3+/Fe4+ Stabilization in a P3‐Type Layered Na0.7[Mn0.5Fe0.4Li0.1]O2 Cathode at High‐Voltages

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Partial Li substitution for Fe in a P3‐Type layered Na0.7[Mn0.5Fe0.4Li0.1]O2 cathode stabilizes the iron redox behavior, particularly at higher charging voltage up to 4.5 V (vs Na/Na+), that enables more reversible sodium‐ion storage capacity and significantly improves capacity retention.
Junghoon Yang   +5 more
wiley   +1 more source

Operational and environmental barriers to centralized composting in two small Brazilian municipalities: A longitudinal study

open access: yesEnvironmental Progress &Sustainable Energy, EarlyView.
Abstract Municipal solid waste management in small cities faces severe logistical and financial barriers regarding organic fraction treatment. This study evaluates biological selective collection in two small Brazilian municipalities (Astorga and Sabáudia), comparing dynamics between gated communities (GC) and public thoroughfares (PT) over an annual ...
André Razente   +3 more
wiley   +1 more source

Paediatric computed tomography diagnostic reference levels in Africa: A systematic review

open access: yesJournal of Medical Radiation Sciences, Volume 72, Issue 1, Page 139-147, March 2025.
Improvements in computed tomography (CT) technology have increased its applications in medical imaging. Variations in the paediatric DRLs indicate that harmonisation and standardisation of paediatric CT protocols are essential for the optimisation of paediatric doses. Abstract Introduction Improvements in computed tomography (CT) technology in terms of
Emmanuel Gyan   +3 more
wiley   +1 more source

Carbon isotope geochemistry of organic matter in volcanic paleosols constrains paleo‐environmental variations

open access: yesJournal of Quaternary Science, EarlyView.
ABSTRACT The Fiorano quarry paleosol developed within the Colli Albani volcanic district (Italy) in the time interval bracketed by the deposition of the Pozzolanelle pyroclastic‐flow unit (365 ± 4 ka) and the emplacement of the Capo di Bove lava flow (277 ± 2 ka).
Eduardo Di Marcantonio   +4 more
wiley   +1 more source

Leveraging Public Transit for Robotic Deliveries: A Column Generation Approach

open access: yesNaval Research Logistics (NRL), EarlyView.
ABSTRACT Autonomous mobile robots (AMRs) are small, electric, wheeled vehicles that operate at pedestrian speeds. In the last‐mile delivery service considered in this study, a fleet of AMRs is deployed across multiple recharging depots within a service area, from which they depart to perform point‐to‐point deliveries. We consider an operational setting
Yishay Shapira, Mor Kaspi
wiley   +1 more source

Home - About - Disclaimer - Privacy