In this work, the synthesis and characterization of novel π‐extended phenazine diimides is reported. The derivatives undergo differential reduction to a dihydrophenazine or Meisenheimer form depending on the reaction conditions employed. The outcome of this work highlights the paramount importance of structural design in determining the nature of the ...
Francesco Rigodanza +7 more
wiley +1 more source
Get a better glimpse on sequential photoreactions of trisnorbornadienes with <sup>19</sup>F NMR spectroscopy. [PDF]
Hebborn JFM +3 more
europepmc +1 more source
Beyond the Edge: Charge‐Transfer Excitons in Organic Donor‐Acceptor Cocrystals
Complex excitonic landscapes in acene–perfluoroacene cocrystals are unveiled by polarization‐resolved optical spectroscopy and many‐body theory. This systematic study of a prototypical model system for weakly interacting donor–acceptor compounds challenges common views of charge‐transfer excitons, providing a refined conceptual framework for ...
Sebastian Anhäuser +6 more
wiley +1 more source
Emerging solid-state cycloaddition chemistry for molecular solar thermal energy storage. [PDF]
Raju C, Nguyen HPQ, Han GGD.
europepmc +1 more source
Mechanochromism of Glassy Polymers Enabled by a Loop‐Forming Supramolecular Mechanophore
The supramolecular mechanophore LOOP is covalently introduced into glassy polymers, capable of reporting force‐induced pre‐failure damage and local fracture events in polymer glasses. Under different mechanical deformation modes, including grinding, tensile stretching, and scratching, LOOP probes irreversible events in polymer glasses through a ...
Linlin Deng +6 more
wiley +1 more source
Scrutinizing the evidence of anthracene toxicity on adrenergic receptor beta-2 and its bioremediation by fungal manganese peroxidase via in silico approaches. [PDF]
Naveed M +8 more
europepmc +1 more source
Degradation in blue MR‐TADF OLEDs originates from high triplet density caused by slow RISC. LDI‐TOF MS directly detects host‐ and emitter‐derived fragments, providing molecular insight into how triplet accumulation drives degradation in the emissive layer. ABSTRACT Blue organic light‐emitting diodes (OLEDs) employing multi‐resonance thermally activated
Min Gyu Jun +5 more
wiley +1 more source
Catalytic Conversion of Lower Olefins to Aromatics Using Zeolite‐Based Catalysts
Zeolite‐catalyzed upgrading of light olefins (C2–C4) into benzene, toluene, and xylenes (BTX) represents a sustainable route to aromatics. This review outlines thermodynamic and mechanistic aspects, the influence of acidity and textural properties of catalysts.
Paresh Butolia +5 more
wiley +1 more source
The Flexibility of Tetra(N-Heterocyclic Carbene) Ligands Controls the Nuclearity and Geometry of Polynuclear M<sup>I</sup>‒NHC Assemblies. [PDF]
Jin GF, Wang F, Hahn FE, Han YF.
europepmc +1 more source
The furan Diels–Alder reaction is a versatile platform for metastable and biobased molecules and materials. By accessing atypical oxanorbornene adducts, we expand furan Diels–Alder chemistry beyond activated addends and show that cycloreversion stability can be tuned over six orders of magnitude, revealing structure–stability relationships that enable ...
Eva Harsevoort +2 more
wiley +1 more source

