Remarkable Formation of Indene Derivatives Upon Friedel–Crafts Acylation Reactions
This shows indene derivatives. Under the reaction conditions of a Friedel–Crafts acylation, alkyl benzenes underwent an unprecedented cyclopentannulation furnishing indene derivatives. Alkylbenzene derivatives react with two equivalents of pivaloyl chloride (PivCl) in the presence of aluminum trichloride under formation of indene derivatives with up to
Leah Bantel +3 more
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Divergent Transport Dynamics of Alkylated versus Unsubstituted Polycyclic Aromatic Hydrocarbons at the Air-Water and Sediment-Water Interfaces at a Legacy Creosote Site. [PDF]
Moran IL +5 more
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Dibenzosuberene‐Winged Polycyclic Aromatic Hydrocarbons
The twisted acene 8, which features two dibenzosuberene “wings”, was prepared by the addition of a crowded aryne to a similarly “winged” cyclopentadienone. Compound 8 is chiral, and it has a high barrier to thermal racemization (ΔG‡rac = 36 kcal/mol), but it undergoes fast photochemical racemization even in ambient light.
Mingshu Xie +3 more
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Catalytic asymmetric [4 + 2] dearomative photocycloadditions of anthracene and its derivatives with alkenylazaarenes. [PDF]
Tian D +5 more
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Vibronic Trimer Design Enhancing Intramolecular Triplet-Exciton Hopping to Accelerate Triplet-Triplet Annihilation for Photon Upconversion. [PDF]
Higashi K +7 more
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Developmental toxicity of alkylated PAHs and substituted phenanthrenes: Structural nuances drive diverse toxicity and AHR activation. [PDF]
Morshead ML +5 more
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B-N Fused Anthracene as Functional Linker for π-Extended Viologens: Near-IR Emission and Electrochromism. [PDF]
Nandi RP, Zuo J, Shibu A, Jäkle F.
europepmc +1 more source
Bicyclic anionic receptors for carboxylates in water. [PDF]
Ren X, Davis AP.
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Bioconjugation Strategies for Revealing the Roles of Glycerophospholipids in Cells
Glycerophospholipids are the main class of phospholipids, essential for membrane structure, compartmentalization, and cellular signaling. To study their roles, innovative probes and advanced bioconjugation strategies have been developed, including by de novo lipid synthesis and bioorthogonal conjugation chemistry.
Brice Beauvais +5 more
wiley +1 more source
Achieving magnetic control of cellular events by introducing non-native radical pair formation. [PDF]
Sessler JL.
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