Scrutinizing the evidence of anthracene toxicity on adrenergic receptor beta-2 and its bioremediation by fungal manganese peroxidase via in silico approaches. [PDF]
Naveed M +8 more
europepmc +1 more source
Pt/C‐Catalyzed Deuteration of Polycyclic Aromatic Hydrocarbons with Suppressed Arene Hydrogenation
An additive‐enabled Pt/C protocol promotes hydrogen–deuterium exchange in fused polycyclic aromatic hydrocarbons (PAHs) in D2O/2‐PrOH at 80 °C. Decalin suppresses undesired ring hydrogenation while accelerating on‐ring H–D exchange, furnishing highly deuterated PAHs (PAHs‐dn).
Naoya Sakurada +6 more
wiley +1 more source
The Flexibility of Tetra(N-Heterocyclic Carbene) Ligands Controls the Nuclearity and Geometry of Polynuclear M<sup>I</sup>‒NHC Assemblies. [PDF]
Jin GF, Wang F, Hahn FE, Han YF.
europepmc +1 more source
Photo- and thermo-responsive complementary metal coordination for the construction of supramolecular polymers. [PDF]
Rao S +8 more
europepmc +1 more source
A new method has been developed for the C–H formylation of aromatic compounds using silyl formates synthesized from CO2 and hydrosilanes. This is the first report on the direct C–H formylation of aromatics with silyl formates. The formylation reactions were promoted by BBr3 or BCl3. The reaction mechanism has been clarified by DFT calculations. Despite
Natsumi Nitta +5 more
wiley +1 more source
Programming Palladium Cage Geometry through Ligand Redox Modulation
A neutral redox‐active exTTF ligand (L) forms a Pd2L4 cage, whereas its oxidized form (Lox) yields a Pd2(Lox)2 macrocycle. Lox further assembles with a dibenzothiophene derivative (L′) into Pd2(Lox)(L′)2 and Pd4(Lox)4(L′)4 architectures. Reduction of Pd2(Lox)2 and Pd2(Lox)(L′)2 restores the parent Pd2L4 cage, enabling redox controlled nuclearity ...
Jennifer Bou Zeid +11 more
wiley +2 more sources
Phytochemistry, Antimicrobial, Analgesic, Antibiofilm, Diuretic Activities, and Acute Toxicity of Bark Extracts From Three Plants (Khaya senegalensis, Ocimum americanum, and Cassytha filiformis) Collected in Benin. [PDF]
Assouma FF +12 more
europepmc +1 more source
Redox‐active guanidines, comprising guanidino‐functionalized aromatics (GFAs) and redox‐active urea azines (RAAs), are electron donors and strong Lewis and Brønsted bases that are used in several applications. They act as redox‐active ligands in bistable coordination compounds and as reagents in dehydrogenative coupling reactions and proton‐coupled ...
Hans‐Jörg Himmel
wiley +1 more source
Two spirobisanthracene‐tetraphenylethene (SBA‐TPE) hybrid compounds are synthesized and their photophysical properties in the solid state reported. Circularly polarized luminescence in aggregates, films and dispersions is evaluated. Circularly polarized luminescence imaging is evaluated over crystals revealing discrimination of different types of ...
José L. Páez +7 more
wiley +2 more sources
Isolation of New Chemical Modulators of the Interaction Between HIV-1 Integrase and the Cellular Restriction Factor GCN2. [PDF]
Torres C +4 more
europepmc +1 more source

