Ion‐Pairing and Counterion Effects in Contemporary Photochemistry
Ion‐pairing and counterion effects have emerged as fundamental yet underexplored determinants of photochemical behavior. Far from inert, counterions, and Coulombic interactions modulate excited‐state dynamics, quenching efficiencies, emission, and catalytic pathways.
Matthias Schmitz, Christoph Kerzig
wiley +1 more source
Comprehensive chromatographic and chemometric profiling of five medicinal South African Bulbine species across leaves, rhizomes, and roots reveals 73 metabolites, including species‐specific phenylanthraquinones, flavonoids, and anthocyanins, that serve as reliable chemical markers for species authentication.
Ramoagi T. Segone +7 more
wiley +1 more source
Tar Removal From Biomass‐Derived Syngas via Scrubbing: A Review on Process and Modeling
This review article surveys contaminant formation and removal in biomass‐derived syngas, with a focus on tar scrubbing. It synthesizes evidence from benchmark plants and compares scrubbing configurations and solvents to assess performance and operating limits.
Simon Brinkmann +2 more
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Bridged Boranoanthracenes: Precursors for Free Oxoboranes through Aromatization-Driven Oxidative Extrusion. [PDF]
Deri S +9 more
europepmc +1 more source
Push–pull substitution activates fluorescence in the weakly emissive phenazine scaffold, producing photostable green‐to‐red emitters via a one‐step annulation. A systematic comparison of positional isomers reveals that the Etter‐rule‐directed hydrogen‐bonding patterns modulate the emission wavelength and crystal packing, while the molecular symmetry ...
Hiroki Sato +7 more
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Regioselective access to B-N Lewis pair-functionalized anthracenes: mechanistic studies and optoelectronic properties. [PDF]
Zuo J +3 more
europepmc +1 more source
Photophysics of a Tetraazaperylene Ligand and Its Heteroleptic Cu(I) Complex
π‐Extension with the tape ligand strongly red‐shifts the metal‐to‐ligand charge transfer transition of Cu(I) diimine‐diphosphine complexes far into the visible, enabling one of the most bathochromic absorptions reported for this class. The synthesis and characterization of Cutape, a heteroleptic Cu(I) complex featuring a π‐extended tetraazaperylene ...
Johannes P. Zurwellen +10 more
wiley +1 more source
Rotaxanes with integrated photoswitches: design principles, functional behavior, and emerging applications. [PDF]
Matsushima JE +4 more
europepmc +1 more source
How to Stabilize Large Soluble (Hetero-)Acenes. [PDF]
Freudenberg J, Bunz UHF.
europepmc +1 more source
From Triplet to Twist: The Photochemical E/Z-Isomerization Pathway of the Near-Infrared Photoswitch peri-Anthracenethioindigo. [PDF]
Hartinger M +6 more
europepmc +1 more source

