Results 131 to 140 of about 218,279 (284)

Protic Poly(Diallylammonium Sulfonate)s: Toward Water‐Processable Fluorine‐Free Ionic Materials

open access: yesMacromolecular Rapid Communications, EarlyView.
A new family of fluorine‐free protic poly(ionic liquids) was synthesized via free‐radical cyclopolymerization of diallylammonium monomers containing sulfonates as counter‐anions. Their properties were found to depend on both cation and anion structure, showing thermal stability up to 300°C, glass transition temperatures between 20°C and 52°C, ionic ...
Yuliana Pairetti   +5 more
wiley   +1 more source

Advances in conjugated porous polymers via high internal phase emulsion templating

open access: yesPolymer International, EarlyView.
This mini‐review highlights the design, synthesis and potential applications of π‐conjugated polyHIPEs, emphasizing their unique hierarchical structure and tunable properties. The work outlines innovative synthetic strategies and explores their promising roles in photocatalysis and environmental remediation, paving the way for future advancements in ...
Julie‐Lisa Malaval   +4 more
wiley   +1 more source

Copolymer Synthesis of N‐Vinylacetamide and 2‐Methylene‐1,3‐Dioxepane Provides a New Degradable Polymer

open access: yesJournal of Polymer Science, Volume 63, Issue 6, Page 1306-1318, 15 March 2025.
ABSTRACT N‐vinylamides, especially noncyclic N‐vinylacetamide (NVA), have been used in various applications such as biomaterials, surfactants, and hydrogels. However, their potential to copolymerize with cyclic ketene acetal (CKA) to create degradable polymers is underexplored.
Mukmin Sapto Pamungkas   +2 more
wiley   +1 more source

Bifunctional Electrocatalysts in Rechargeable Lithium‐Gas Batteries: Material Evolution and Mechanistic Insights from Metal‐Free Carbons to Carbon‐Supported Single‐Atom Sites

open access: yesSmall, EarlyView.
This review charts the material evolution of bifunctional electrocatalysts for rechargeable lithium‐gas batteries. It highlights the journey from heteroatom‐doped, metal‐free carbon architectures to precision‐engineered carbon‐supported single‐atom sites. The discussion focuses on mechanistic insights into how these catalysts govern reversible O2, CO2,
Daming Ren   +5 more
wiley   +1 more source

Sodium‐Based Battery Component Design: Imitating Lithium or Forging New Paths?

open access: yesSmall, EarlyView.
This Perspective elucidates the decisive yet underexplored impact of cation chemistry, Na+ vs. Li+ charge carriers, on the design, selection, and formulation of their corresponding battery systems, addressing common misconceptions and the pitfalls of overreliance on Li+ design principles. Leveraging the unique characteristics of Na+, it comprehensively
Xingxing Wang   +13 more
wiley   +1 more source

Scandium Doping and Coating for Improving O3‐NaNi1/2Mn1/2O2 Electrode in Sodium Battery

open access: yesSmall, EarlyView.
Scandium incorporation into O3‐Na[Ni1/2Mn1/2]O2 enhances cycling stability through distinct bulk and interfacial mechanisms. Bulk Sc3+ doping stabilizes the lattice and suppresses the O′3 phase, while Sc2O3 coating mitigates interfacial degradation. Together, these strategies markedly improve long‐term performance, offering a pathway to design durable ...
Kodai Moriya   +5 more
wiley   +1 more source

Super‐Electron‐Donor Polymers: From Monomer Design to Redox Functionality

open access: yesSmall, EarlyView.
2,2'‐Bipyridinylidenes are known for their “super‐electron‐donor” properties and have therefore been used beyond the field of organic synthesis. Their two‐electron redox process at a low potential of 1.8 V vs. Li/Li+ makes them attractive negative p‐type electrode‐active materials.
Luisa Rzesny   +9 more
wiley   +1 more source

Bromination of Alkenes and Related Compounds by Use of Benzyltrimethylammonium Tribromide in Aprotic and Protic Solvents

open access: yes
The reaction of alkenes and related compounds (1) with benzyltrimethyl-ammonium tribromide (BTMA Br_3) in aprotic solvents such as dichloromethane and chloroform gave 1, 2-dibromo adducts in fairly good yields.
柿並, 孝明   +12 more
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