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Enhanced Zinc Deposition and Dendrite Suppression in Aqueous Zinc‐Ion Batteries Via Citric Acid‐Aspartame Electrolyte Additives

Advanced Energy Materials
Despite the advantages of low cost, safety, and environmental friendliness, aqueous zinc‐ion batteries (AZIBs) encounter challenges such as zinc dendrite formation, severe side reactions, and electrolyte instability.
Tao Xue   +7 more
semanticscholar   +1 more source

Aqueous Zinc-Ion Batteries with Boosted Stability and Kinetics Under a Wide Temperature Range.

Angewandte Chemie
Sustainable aqueous zinc ion batteries (AZIBs) necessitate a wide operational temperature range to ensure practicability, yet achieving this often compromises either reaction kinetics at low temperatures or cycling stability at high temperatures. Here we
Lei Zhang   +7 more
semanticscholar   +1 more source

An Aqueous Zinc‐Ion Battery Based on Copper Hexacyanoferrate

ChemSusChem, 2014
AbstractA new zinc‐ion battery based on copper hexacyanoferrate and zinc foil in a 20 mM solution of zinc sulfate, which is a nontoxic and noncorrosive electrolyte, at pH 6 is reported. The voltage of this novel battery system is as high as 1.73 V. The system shows cyclability, rate capability, and specific energy values near to those of lithium‐ion ...
Rafael, Trócoli, Fabio, La Mantia
openaire   +2 more sources

Advances in Aqueous Zinc Ion Batteries based on Conversion Mechanism: Challenges, Strategies, and Prospects.

Small
Recently, aqueous zinc-ion batteries with conversion mechanisms have received wide attention in energy storage systems on account of excellent specific capacity, high power density, and energy density.
Huiting Xu   +10 more
semanticscholar   +1 more source

“Soggy‐Sand” Chemistry for High‐Voltage Aqueous Zinc‐Ion Batteries

Advanced Materials, 2023
AbstractThe narrow electrochemical stability window, deleterious side reactions, and zinc dendrites prevent the use of aqueous zinc‐ion batteries. Here, aqueous “soggy‐sand” electrolytes (synergistic electrolyte‐insulator dispersions) are developed for achieving high‐voltage Zn‐ion batteries.
Rongyu Deng   +7 more
openaire   +2 more sources

Cathode materials for aqueous zinc-ion batteries: A mini review

Journal of Colloid and Interface Science, 2022
Although lithium-ion batteries (LIBs) have many advantages, they cannot satisfy the demands of numerous large energy storage industries owing to their high cost, low security, and low resource richness. Aqueous zinc-ion batteries (ZIBs) with low cost, high safety, and high synergistic efficiency have attracted an increasing amount of attention and are ...
Tao, Zhou   +7 more
openaire   +2 more sources

Steric-hindrance Effect Tuned Ion Solvation Enabling High Performance Aqueous Zinc Ion Batteries.

Angewandte Chemie
Despite many additives have been reported for aqueous zinc ion batteries, steric- hindrance effect of additives and its correlation with Zn2+ solvation structure have been rarely reported. Herein, large-sized sucrose biomolecule is selected as a paradigm
Haozhen Dou   +8 more
semanticscholar   +1 more source

Tuning Proton Insertion Chemistry for Sustainable Aqueous Zinc‐Ion Batteries

Small, 2023
AbstractRechargeable aqueous zinc‐ion batteries (ZIBs) have emerged as an alternative to lithium‐ion batteries due to their affordability and high level of safety. However, their commercialization is hindered by the low mass loading and irreversible structural changes of the cathode materials during cycling.
Gyutae Nam   +10 more
openaire   +2 more sources

MnO2 superstructure cathode with boosted zinc ion intercalation for aqueous zinc ion batteries

Journal of Colloid and Interface Science
The simultaneous intercalation of protons and Zn$^{2+}$ ions in aqueous electrolytes presents a significant obstacle to the widespread adoption of aqueous zinc ion batteries (AZIBs) for large-scale use, a challenge that has yet to be overcome. To address this, we have developed a MnO$_2$/tetramethylammonium (TMA) superstructure with an enlarged ...
Aina Zhang   +8 more
openaire   +4 more sources

Reversible Oxygen Redox Chemistry in Aqueous Zinc‐Ion Batteries

Angewandte Chemie, 2019
AbstractRechargeable aqueous zinc‐ion batteries (ZIBs) are promising energy‐storage devices owing to their low cost and high safety. However, their energy‐storage mechanisms are complex and not well established. Recent energy‐storage mechanisms of ZIBs usually depend on cationic redox processes.
Fang Wan   +7 more
openaire   +2 more sources

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