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Overlooked calendar issues of aqueous zinc metal batteries

Joule
Although the zinc metal plating and stripping chemistry offers a high specific capacity, this process suffers from poor reversibility, a crucial factor for long-term energy storage. Most studies so far have been focusing on cyclic aging but overlooked the impact of calendar aging on zinc metal behavior.
Bao Zhang, Hong Jin Fan
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Interfacial ionic effects in aqueous zinc metal batteries

Energy Storage Materials
Zn metals anodes (ZMAs) are most attractive for emerging aqueous zinc metal batteries (AZMBs). However, the practical application of AZMBs is still impeded by various formidable issues like uncontrolled Zn dendritic growth, hydrogen evolution reaction, and severe corrosion of ZMAs.
Chun Chen   +6 more
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Organic Cations Texture Zinc Metal Anodes for Deep Cycling Aqueous Zinc Batteries

Advanced Materials
AbstractManipulating the crystallographic orientation of zinc (Zn) metal to expose more (002) planes is promising to stabilize Zn anodes in aqueous electrolytes. However, there remain challenges involving the non‐epitaxial electrodeposition of highly (002) textured Zn metal and the maintenance of (002) texture under deep cycling conditions.
Guoqiang Ma   +9 more
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High-entropy materials for aqueous zinc metal batteries

Energy & Environmental Science
This review explores the potential and effective application paths of HEMs in AZIBs, aiming to break the constraints in AZIBs and pave the way toward the development of high-performance AZIBs.
Xiaomin Han   +8 more
openaire   +1 more source

Bifunctional gel coating for stabilizing zinc metal anodes in aqueous zinc-ion batteries

Journal of Colloid and Interface Science
Currently, the zinc anode faces significant challenges such as dendrite growth, corrosion, and hydrogen evolution, which severely limit the practical applications of aqueous zinc-ion batteries. To address these issues, this study designed a zinc anode (denoted as CG@Zn) coated with a gel composed of carboxymethyl cellulose sodium (CMC) and glucose ...
Zhipeng, Liu   +7 more
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Electrolyte Engineering for Aqueous Zinc Metal Batteries

Zn symmetric cell can run for more than 3000 h under the current density of 2 mA cm-2. When zinc anodes were coupled with an activated carbon cathode with a mass loading of 8 mg cm-2, the powering device showed high reversibility. Although additives can enhance the performance of zinc metal anodes, their low concentration limits their ability to ...
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Crystallographic Customization of Zinc Anode for High Performance Aqueous Metal Batteries

Nano Letters
Aqueous zinc metal batteries (AZMBs) are an energy storage system that is expected to replace traditional lithium batteries. However, the practical application of AZMBs is hampered by some inherent drawbacks. Herein, an amino acid additive with a screening property is introduced.
Ji-Zun Zhang   +8 more
openaire   +2 more sources

Gradient Structured Separator Enables Stable Aqueous Zinc Metal Batteries

Nano Letters
Developing a functional separator is an important strategy to improve the electrochemical performance of the Zn anode by suppressing the Zn dendrite growth and parasitic side reactions, thus advancing the aqueous zinc-ion batteries. Herein, we experimentally realize functional separator with gradient-structure based on CeF3 nanoparticles functionalized
Zehua Zhao   +7 more
openaire   +2 more sources

The road ahead for hydrogel electrolytes in aqueous zinc metal batteries

Iontronics
Hydrogel electrolytes, enabled by tunable polymer networks, mechanical robustness, and water confinement, provide a promising platform for stabilizing Zn metal anodes in aqueous zinc metal batteries. Progress can be broadly viewed through three coupled modules: microenvironment control to regulate water activity and Zn<sup>2+</sup> ...
Zhenzhen Wang   +6 more
openaire   +1 more source

Transition metal phosphide-based oxygen electrocatalysts for aqueous zinc–air batteries

Chemical Communications
This feature article highlights the recent advances, challenges and future scope of transition metal phosphides as bifunctional oxygen electrocatalysts for aqueous zinc–air batteries.
Santanu Ghora   +4 more
openaire   +2 more sources

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