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Succinonitrile Electrolyte Additive for Stabilizing Aqueous Zinc Metal Batteries
ACS Applied Materials & InterfacesThe utilization of water electrolytes in zinc-ion batteries offers the advantages of enhanced safety, reduced cost, and improved environmental friendliness, rendering them an optimal choice for replacing lithium-ion batteries. Nevertheless, the conventional zinc sulfate electrolyte fails to meet stringent requirements.
Yang Yu +9 more
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Improving Aqueous Zinc Ion Batteries with Alkali Metal Ions
ACS Applied Materials & InterfacesAqueous zinc (Zn) ion batteries have received broad attention recently. However, their practical application is limited by severe Zn dendrite growth and the hydrogen evolution reaction. In this study, three alkali metal ions (Li+, Na+, and K+) are added in ZnSO4 electrolytes, which are subjected to electrochemical measurements and molecular dynamics ...
Mengyuan Xue +4 more
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High-entropy materials for aqueous zinc metal batteries
Energy & Environmental ScienceThis review explores the potential and effective application paths of HEMs in AZIBs, aiming to break the constraints in AZIBs and pave the way toward the development of high-performance AZIBs.
Xiaomin Han +8 more
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Overlooked calendar issues of aqueous zinc metal batteries
JouleAlthough the zinc metal plating and stripping chemistry offers a high specific capacity, this process suffers from poor reversibility, a crucial factor for long-term energy storage. Most studies so far have been focusing on cyclic aging but overlooked the impact of calendar aging on zinc metal behavior.
Bao Zhang, Hong Jin Fan
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Interfacial ionic effects in aqueous zinc metal batteries
Energy Storage MaterialsZn metals anodes (ZMAs) are most attractive for emerging aqueous zinc metal batteries (AZMBs). However, the practical application of AZMBs is still impeded by various formidable issues like uncontrolled Zn dendritic growth, hydrogen evolution reaction, and severe corrosion of ZMAs.
Chun Chen +6 more
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Organic Cations Texture Zinc Metal Anodes for Deep Cycling Aqueous Zinc Batteries
Advanced MaterialsAbstractManipulating the crystallographic orientation of zinc (Zn) metal to expose more (002) planes is promising to stabilize Zn anodes in aqueous electrolytes. However, there remain challenges involving the nonâepitaxial electrodeposition of highly (002) textured Zn metal and the maintenance of (002) texture under deep cycling conditions.
Guoqiang Ma +9 more
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Bifunctional gel coating for stabilizing zinc metal anodes in aqueous zinc-ion batteries
Journal of Colloid and Interface ScienceCurrently, the zinc anode faces significant challenges such as dendrite growth, corrosion, and hydrogen evolution, which severely limit the practical applications of aqueous zinc-ion batteries. To address these issues, this study designed a zinc anode (denoted as CG@Zn) coated with a gel composed of carboxymethyl cellulose sodium (CMC) and glucose ...
Zhipeng, Liu +7 more
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Crystallographic Customization of Zinc Anode for High Performance Aqueous Metal Batteries
Nano LettersAqueous zinc metal batteries (AZMBs) are an energy storage system that is expected to replace traditional lithium batteries. However, the practical application of AZMBs is hampered by some inherent drawbacks. Herein, an amino acid additive with a screening property is introduced.
Ji-Zun Zhang +8 more
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Gradient Structured Separator Enables Stable Aqueous Zinc Metal Batteries
Nano LettersDeveloping a functional separator is an important strategy to improve the electrochemical performance of the Zn anode by suppressing the Zn dendrite growth and parasitic side reactions, thus advancing the aqueous zinc-ion batteries. Herein, we experimentally realize functional separator with gradient-structure based on CeF3 nanoparticles functionalized
Zehua Zhao +7 more
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The road ahead for hydrogel electrolytes in aqueous zinc metal batteries
IontronicsHydrogel electrolytes, enabled by tunable polymer networks, mechanical robustness, and water confinement, provide a promising platform for stabilizing Zn metal anodes in aqueous zinc metal batteries. Progress can be broadly viewed through three coupled modules: microenvironment control to regulate water activity and Zn<sup>2+</sup> ...
Zhenzhen Wang +6 more
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