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Chemistry – A European Journal, 2014
AbstractNo organic molecules with electron affinities near or above those of halogens are known. We show for the first time that aromaticity rules can be used to design molecules with electron affinities far exceeding those of halogen atoms either by tailoring the ligands of cyclopentadienyl or by multiple benzoannulations of cyclopentadienyl in ...
Child, Brandon +3 more
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AbstractNo organic molecules with electron affinities near or above those of halogens are known. We show for the first time that aromaticity rules can be used to design molecules with electron affinities far exceeding those of halogen atoms either by tailoring the ligands of cyclopentadienyl or by multiple benzoannulations of cyclopentadienyl in ...
Child, Brandon +3 more
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Chemistry – An Asian Journal, 2018
AbstractAromatic aminocatalysis refers to transformations that employ aromatic amines, such as anilines or aminopyridines, as catalysts. Owing to the conjugation of the amine moiety with the aromatic ring, aromatic amines demonstrate distinctive features in aminocatalysis compared with their aliphatic counterparts.
Jian Lv +4 more
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AbstractAromatic aminocatalysis refers to transformations that employ aromatic amines, such as anilines or aminopyridines, as catalysts. Owing to the conjugation of the amine moiety with the aromatic ring, aromatic amines demonstrate distinctive features in aminocatalysis compared with their aliphatic counterparts.
Jian Lv +4 more
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Accounts of Chemical Research, 2007
The first example of a family of related aromatic metallacycles has been synthesized, and the physical and chemical properties of its individual members have been investigated. The metallacyclic rings in these compounds are, in general, constructed from pentadienyl- or heteropentadienyliridium precursors via C-H bond activation processes. The molecules
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The first example of a family of related aromatic metallacycles has been synthesized, and the physical and chemical properties of its individual members have been investigated. The metallacyclic rings in these compounds are, in general, constructed from pentadienyl- or heteropentadienyliridium precursors via C-H bond activation processes. The molecules
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Carbohydrate Research, 2006
AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
Mårten, Jacobsson +2 more
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AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
Mårten, Jacobsson +2 more
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Dehalogenation of Aromatics by Nucleophilic Aromatic Substitution
Environmental Science & Technology, 2014Nucleophilic aromatic substitution has been implicated as a mechanism for both the biotic and abiotic hydrodehalogenation of aromatics. Two mechanisms for the aqueous dehalogenation of aromatics involving nucleophilic aromatic substitution with hydride as a nucleophile are investigated using a validated density functional and continuum solvation ...
Daniel, Sadowsky +2 more
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“Carbo-aromaticity” and novel carbo-aromatic compounds
Chemical Society Reviews, 2015Recent advances in experimental and theoretical studies ofcarbo-benzene derivatives, along with the proposition of a generalization of the definition of aromaticity to the two-membered π-rings of triple bonds, suggest relevance for the notion of “carbo-aromaticity”.
Kévin, Cocq +3 more
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Polynuclear aromatic hydrocarbons
Environmental Science & Technology, 1981Polynuclear aromatic hydrocarbons (PAHs) can enter the environment in several ways, primarily through the incomplete combustion of carbonaceous materials or through processes that convert coal into synthetic fuels. Other sources of PAHs include the manufacture of carbon black, creosote, soot, vehicular emissions (especially diesel), residual oil, and ...
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Aromaticity and Electrophilic Aromatic Substitution
1977The meaning of the word aromaticity has evolved as understanding of the reason for the special properties of benzene and other aromatic molecules has deepened. Originally, aromaticity was associated with a special chemical reactivity.1 The aromatic hydrocarbons were considered to be those unsaturated systems that underwent substitution reactions in ...
Francis A. Carey, Richard J. Sundberg
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