Results 71 to 80 of about 9,110 (204)

Mid‐infrared Spectroscopy of Protonated Benzonitrile, 2‐Cyanonaphthalene, and 9‐Cyanoanthracene for Astrochemical Consideration

open access: yesChemPhysChem, Volume 26, Issue 24, December 16, 2025.
Experimental infrared absorption spectra of three protonated cyano‐substituted PAHs measured by infrared multiple photon dissociation using the free‐electron laser Free‐Electron Laser for Infrared eXperiments are studied. These spectra are compared to an emission spectrum measured by JWST, and the largest measured protonated cyano‐PAH, cyanoanthracene,
Anne P. Rasmussen   +6 more
wiley   +1 more source

Kinetics and Thermodynamics of Tautomerization Reactions of 1,1‐ and 1,2‐Ethenediols

open access: yesInternational Journal of Chemical Kinetics, Volume 57, Issue 12, Page 687-696, December 2025.
ABSTRACT Tautomerism is a common phenomenon amongst organic molecules with easily interconvertible isomers, which can impact drug action and toxicity. Here we are interested in the enols of carboxylic acids, which are known to be much less stable than their acid counterparts.
Judith Würmel, John M. Simmie
wiley   +1 more source

The chemical connection between 67P/C-G and IRAS 16293-2422

open access: yes, 2018
The chemical evolution of a star- and planet-forming system begins in the prestellar phase and proceeds across the subsequent evolutionary phases. The chemical trail from cores to protoplanetary disks to planetary embryos can be studied by comparing ...
Altwegg, Kathrin   +4 more
core   +1 more source

Satellites and Small Bodies With ALMA: Insights Into Solar System Formation and Evolution

open access: yesAGU Advances, Volume 6, Issue 6, December 2025.
Abstract Our understanding of the formation and evolution of planetary systems has made major advances in the past decade. This progress has been driven in large part by the Atacama Large Millimeter/submillimeter Array (ALMA), which has given us an unprecedented view of solar system bodies themselves, and of the structure and chemistry of forming ...
Katherine de Kleer   +3 more
wiley   +1 more source

Theoretical approaches for studying Astrochemistry

open access: yesEPJ Web of Conferences, 2012
The most popular ab initio theoretical approaches that are used to study the gas phase astrochemical reactivity are presented. The methods that are needed for the electronic calculation and the statistical approaches that are used for determining the ...
Talbi D.
doaj   +1 more source

Atomistic Modeling of Methyl Formate and Glycolaldehyde Formation on Interstellar Dirty Ice Mantles via a “Radical + Ice” Mechanism

open access: yesChemPlusChem, Volume 90, Issue 11, November 10, 2025.
The presence of interstellar complex organic molecules (COMs) has been baffling astrochemists for a long time. Methyl formate and glycolaldehyde are widely detected but their abundances mismatch kinetic astrochemical model predictions. Here, the formation of these two COMs is characterized onto a mixed ice surface, highlighting the importance of ...
Jessica Perrero   +3 more
wiley   +1 more source

Nature's Starships II: Simulating the Synthesis of Amino Acids in Meteorite Parent Bodies

open access: yes, 2015
Carbonaceous chondrite meteorites are known for having high water and organic material contents, including amino acids. Here we address the origin of amino acids in the warm interiors of their parent bodies (planetesimals) within a few million years of ...
Cobb, Alyssa K.   +2 more
core   +1 more source

Radioprotective Efficacy of Jujube Aqueous Extract and Arbutin: Synergistic Antioxidant and Anti‐Apoptotic Mechanisms in Radiation Injury

open access: yesFood Science &Nutrition, Volume 13, Issue 10, October 2025.
JAE demonstrates potent antioxidant activity and protects against radiation‐induced lung injury. Proteomic reveals JAE modulates apoptosis and oxidative stress pathways for radioprotection. JAE demonstrates broad cellular protection against UVC damage in lung and skin cell models.
Liping Wang   +5 more
wiley   +1 more source

Cosmic-ray induced diffusion in interstellar ices

open access: yes, 2014
Cosmic rays are able to heat interstellar dust grains. This may enhance molecule mobility in icy mantles that have accumulated on the grains in dark cloud cores.
Kalvans, Juris
core   +2 more sources

UV–Vis Spectra of Carbonic Acid: Rationalizing Experimental Redshifts between Monomer and Bulk based on (H2CO3)n Calculations

open access: yesChemPhysChem, Volume 26, Issue 18, September 19, 2025.
In bulk carbonic acid (e.g., in interstellar icy dust grains) cluster formation produces two distinct UV‐Vis spectral features redshifted by ≈2 eV (25 nm) and by ≈5 eV (80 nm) compared to gas phase single molecule carbonic acid 's adiabatic ionization energy. Theory and experiment were used to investigate the origin of these shifts.
Dennis F. Dinu   +7 more
wiley   +1 more source

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