Synthesis of cellulose based graft polymers using metal-catalyzed living radical polymerization [PDF]
A copolymer composed of styrene and acrylonitrile was grafted onto cellulose backbone by free radical polymerization and atom transfer radical polymerization (ATRP) method.
مجتبی عباسیان +1 more
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Metal-Free Atom Transfer Radical Polymerization [PDF]
Overcoming the challenge of metal contamination in traditional ATRP systems, a metal-free ATRP process, mediated by light and catalyzed by an organic-based photoredox catalyst, is reported. Polymerization of vinyl monomers are efficiently activated and deactivated with light leading to excellent control over the molecular weight, polydispersity, and ...
Treat, Nicolas J +7 more
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Atom Transfer Radical Polymerization of Styrene in Presence of Mesoporous Silica Nanoparticles: Application of Reverse, Simultaneous Reverse and Normal Initiation Techniques [PDF]
Atom transfer radical polymerization (ATRP) of styrene in presence of mesoporous silica nanoparticles was carried out at 110 °C. Reverse atom transfer radical polymerization (RATRP) and simultaneous reverse and normal initiation for atom transfer radical
Khezrollah Khezri +3 more
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Surface-initiated controlled radical polymerization is a powerful strategy to tailor the chemical and physical surface properties of materials.
Laurent Lavanant, Harm-Anton Klok
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Advances in Organocatalyzed Atom Transfer Radical Polymerization
Atom transfer radical polymerization (ATRP) is one of the most robust tools to prepare well-defined polymers with precise topologies and architectures. Although series of improved ATRP methods have been developed to decrease the metal catalyst loading to
Xin Hu, Ning Zhu, Kai Guo
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Polylactic acid-based membranes received considerable attention due to its novel biocompatibility, renewability, and biodegradability. In this study, PLA electrospun nanofibrous membrane was prepared and 2-dimethylaminoethyl methacrylate (DMAEMA) was ...
Muhammad Mushtaq +7 more
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Synthesis of novel organocatalyzed phenoxazine for free metal atom transfer radical polymerization [PDF]
In this research, a novel organic photocatalyst of 10-(Perylene-3-yl-10H-Phenoxazine (PHP) has been synthesized successfully from perylene and phenoxazine via Buchwald-Hartwig C-N coupling.
Thu Hoang Vo +7 more
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Cellulose Modification Through Grafting of Polyacrylonitrile by Atom Transfer Radical Polymerization [PDF]
In addition to properties such as biocompatibility and biodegradability, cellulosic natural fibers have a higher strength property than the synthetic polymers and glass fibers. So they are suitable alternatives to synthetic and glass fibers.
Mojtaba Abbasian +3 more
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Numerical Simulation of Atom-Transfer Radical Polymerization of tert-butyl Methacrylate [PDF]
Block copolymers based on tert-butyl methacrylate (tBMA) have many uses, such as thermo‐responsive polymers, amphiphilic copolymers, and many applications in the medical field.
Fiorella Zenaida Fernandez Herrera +1 more
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Atom Transfer RaAtom Transfer Radical Polymerization of Methyl Methacrylate Using Bis(2-dodecylsulfanyl-ethyl)-Amine/Copper Bromide: Kinetic Study [PDF]
Hypothesis: In controlled polymerization methods, atom transfer radical polymerization (ATRP) is one of the most successful methods for the polymerization of various monomers with the controlled pattern. Effect of some important parameters on kinetics of
Farnoosh Karimi +2 more
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