Photoinduced Miniemulsion Atom Transfer Radical Polymerization [PDF]
ACS Macro Letters, 2018 Photomediated atom transfer radical polymerization (photoATRP) of (meth)acrylic monomers was conducted in miniemulsion media. The polymerization procedures took advantage of an ion-pair catalyst formed by interaction of Cu/TPMA2 (TPMA = tris(2-pyridylmethyl)amine) and an anionic surfactant, sodium dodecyl sulfate (SDS).
Yi Wang +2 more
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Synthesis of cellulose based graft polymers using metal-catalyzed living radical polymerization [PDF]
شیمی کاربردی روز, 2016 A copolymer composed of styrene and acrylonitrile was grafted onto cellulose backbone by free radical polymerization and atom transfer radical polymerization (ATRP) method.
مجتبی عباسیان +1 more
doaj +1 more source
Metal-Free Atom Transfer Radical Polymerization [PDF]
Journal of the American Chemical Society, 2014 Overcoming the challenge of metal contamination in traditional ATRP systems, a metal-free ATRP process, mediated by light and catalyzed by an organic-based photoredox catalyst, is reported. Polymerization of vinyl monomers are efficiently activated and deactivated with light leading to excellent control over the molecular weight, polydispersity, and ...
Treat, Nicolas J +7 more
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Atom Transfer Radical Polymerization of Styrene in Presence of Mesoporous Silica Nanoparticles: Application of Reverse, Simultaneous Reverse and Normal Initiation Techniques [PDF]
علوم و تکنولوژی پلیمر, 2014 Atom transfer radical polymerization (ATRP) of styrene in presence of mesoporous silica nanoparticles was carried out at 110 °C. Reverse atom transfer radical polymerization (RATRP) and simultaneous reverse and normal initiation for atom transfer radical
Khezrollah Khezri +3 more
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CHIMIA, 2008 Surface-initiated controlled radical polymerization is a powerful strategy to tailor the chemical and physical surface properties of materials.
Laurent Lavanant, Harm-Anton Klok
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Catalytic polymeric nanoreactors : more than a solid supported catalyst [PDF]
, 2012 Polymeric nanostructures can be synthesized where the catalytic motif is covalently attached within the core domain and protected from the environment by a polymeric shell.
Bosman, Liu, Wang, Yan
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Advances in Organocatalyzed Atom Transfer Radical Polymerization
Advances in Polymer Technology, 2019 Atom transfer radical polymerization (ATRP) is one of the most robust tools to prepare well-defined polymers with precise topologies and architectures. Although series of improved ATRP methods have been developed to decrease the metal catalyst loading to
Xin Hu, Ning Zhu, Kai Guo
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Controlled atom transfer radical polymerization of MMA onto the surface of high-density functionalized graphene oxide [PDF]
, 2014 We report on the grafting of poly(methyl methacrylate) (PMMA) onto the surface of high-density functionalized graphene oxides (GO) through controlled radical polymerization (CRP). To increase the density of surface grafting, GO was first diazotized (DGO),
Jin Chung, Mukesh Kumar, Seung Hur
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Supramolecular control over self-assembly and double thermoresponsive behavior of an amphiphilic block copolymer [PDF]
, 2020 A poly(ethylene glycol)-b-poly[N, N-dimethylacrylamide-ran-2-acrylamidoethyl nonanoate] (PEG-b-P(DMA-AAEN)) block copolymer has been demonstrated to show double thermoresponsive behavior in aqueous solution in the presence of hydroxypropylated ...
Hoogenboom, Richard +5 more
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Cellulose Modification Through Grafting of Polyacrylonitrile by Atom Transfer Radical Polymerization [PDF]
علوم و تکنولوژی پلیمر, 2015 In addition to properties such as biocompatibility and biodegradability, cellulosic natural fibers have a higher strength property than the synthetic polymers and glass fibers. So they are suitable alternatives to synthetic and glass fibers.
Mojtaba Abbasian +3 more
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