Ultrasound-Mediated Atom Transfer Radical Polymerization (ATRP). [PDF]
Ultrasonic agitation is an external stimulus, rapidly developed in recent years in the atom transfer radical polymerization (ATRP) approach. This review presents the current state-of-the-art in the application of ultrasound in ATRP, including an initially-developed, mechanically-initiated solution with the use of piezoelectric nanoparticles, that next ...
Zaborniak I, Chmielarz P.
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Progress in the Design and Application of Chemical and Biological Sensors Based on Atom Transfer Radical Polymerization [PDF]
Atom transfer radical polymerization (ATRP) is a leading reversible deactivation radical polymerization method. It has become an emerging technology to synthesize well-defined, tailor-made polymers, promoting the development of advanced materials (e.g ...
Ning Xia +4 more
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Synthesis of PMMA-b-PU-b-PMMA tri-block copolymers through ARGET ATRP in the presence of air [PDF]
ARGET (activators regenerated by electron transfer) ATRP (atom transfer radical polymerization) has been successfully performed (in flasks fitted with rubber septa without the need for use of Schlenk line) in the presence of limited amount of air and ...
P. Krol, P. Chmielarz
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Organocatalyzed Atom Transfer Radical Polymerization (O-ATRP) Using a Super-Reducing Photoredox Catalyst. [PDF]
Abstract The development of highly reducing photoredox catalysts (PCs) has brought forth new approaches to activating strong chemical bonds for small molecule and polymer synthesis. Organocatalyzed atom transfer radical polymerization (O‐ATRP) is a polymerization methodology that uses organic PCs for the synthesis of well‐defined ...
Zhao Y +9 more
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Preparation of Polyacrylamide with Improved Tacticity and Low Molecular Weight Distribution [PDF]
Polyacrylamide with improved tacticity and low molecular weight distribution was obtained via stereospecific atom transfer radical polymerization (ATRP) using the mixture of Lewis acids Y(OTf)3 and AlCl3 in a certain ratio as stereospecific catalyst and ...
Jiang Jianguo +4 more
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Atom Transfer Radical Polymerization of Styrene in Presence of Mesoporous Silica Nanoparticles: Application of Reverse, Simultaneous Reverse and Normal Initiation Techniques [PDF]
Atom transfer radical polymerization (ATRP) of styrene in presence of mesoporous silica nanoparticles was carried out at 110 °C. Reverse atom transfer radical polymerization (RATRP) and simultaneous reverse and normal initiation for atom transfer radical
Khezrollah Khezri +3 more
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Synthesis of cellulose based graft polymers using metal-catalyzed living radical polymerization [PDF]
A copolymer composed of styrene and acrylonitrile was grafted onto cellulose backbone by free radical polymerization and atom transfer radical polymerization (ATRP) method.
مجتبی عباسیان +1 more
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Metal-free atom transfer radical polymerization with ppm catalyst loading under sunlight
Organocatalytic atom transfer radical polymerization (O-ATRP) is attractive due to its metal-free nature but catalysts are rarely applied at a low loading. Here the authors introduce a catalyst design logic based on heteroatom-doping of polycyclic arenes,
Qiang Ma +5 more
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Iron Catalysts in Atom Transfer Radical Polymerization
Catalysts are essential for mediating a controlled polymerization in atom transfer radical polymerization (ATRP). Copper-based catalysts are widely explored in ATRP and are highly efficient, leading to well-controlled polymerization of a variety of ...
Sajjad Dadashi-Silab +1 more
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Modern methods of controlled radical polymerization for obtaining branched polymers of acrylamide, acrylic acid and (met)acrylates [PDF]
A search and analysis has been carried out of English-language 2005–2020 scientifi c literature devoted to methods of obtaining branched (co)polymers of acrylamide, acrylic acid and (met)acrylates in order to obtain novel materials with ...
Bayburdov, Telman А. +1 more
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