Synthesis of novel organocatalyzed phenoxazine for free metal atom transfer radical polymerization [PDF]
In this research, a novel organic photocatalyst of 10-(Perylene-3-yl-10H-Phenoxazine (PHP) has been synthesized successfully from perylene and phenoxazine via Buchwald-Hartwig C-N coupling.
Thu Hoang Vo +7 more
doaj +1 more source
Combinatorial biomaterials discovery strategy to identify new macromolecular cryoprotectants [PDF]
Cryoprotective agents (CPAs) are typically solvents or small molecules, but there is a need for innovative CPAs to reduce toxicity and increase cell yield, for the banking and transport of cells.
Gibson, Matthew I. +4 more
core +2 more sources
Polylactic acid-based membranes received considerable attention due to its novel biocompatibility, renewability, and biodegradability. In this study, PLA electrospun nanofibrous membrane was prepared and 2-dimethylaminoethyl methacrylate (DMAEMA) was ...
Muhammad Mushtaq +7 more
doaj +1 more source
Numerical Simulation of Atom-Transfer Radical Polymerization of tert-butyl Methacrylate [PDF]
Block copolymers based on tert-butyl methacrylate (tBMA) have many uses, such as thermo‐responsive polymers, amphiphilic copolymers, and many applications in the medical field.
Fiorella Zenaida Fernandez Herrera +1 more
doaj +1 more source
The First Example of Tb-3-Containing Metallopolymer-Type Hybrid Materials with Efficient and High Color-Purity Green Luminescence [PDF]
In the series of homo-leptic trinuclear complexes {[Ln(3)(L)(4)Cl-4(MeOH)(H2O)]center dot Cl} (Ln = La, 1; Ln = Eu, 2; Ln = Tb, 3 or Ln = Gd, 4) self-assembled from the allyl-modified benzimidazole-type ligand HL (4-allyl-2-(1H-benzo[d]imidazol-2-yl)-6 ...
Feng, Heini +9 more
core +1 more source
Atom Transfer RaAtom Transfer Radical Polymerization of Methyl Methacrylate Using Bis(2-dodecylsulfanyl-ethyl)-Amine/Copper Bromide: Kinetic Study [PDF]
Hypothesis: In controlled polymerization methods, atom transfer radical polymerization (ATRP) is one of the most successful methods for the polymerization of various monomers with the controlled pattern. Effect of some important parameters on kinetics of
Farnoosh Karimi +2 more
doaj +1 more source
Atom transfer radical polymerization of MMA with a macromolecular ligand in a fluorinated solvent and in supercritical carbon dioxide [PDF]
Macromolecular fluorinated ligands were prepared according to a three-step strategy that consists of the random copolymerization of heptadecafluorodecyl acrylate and 2-hydroxyethylacrylate, followed by the esterification of the pendant hydroxyl groups ...
Calberg, Cédric +4 more
core +1 more source
PNIPAM grafted surfaces through ATRP and RAFT polymerization: Chemistry and bioadhesion [PDF]
Biomaterials surface design is critical for the control of materials and biological system interactions.Being regulated by a layer of molecular dimensions, bioadhesion could be effectively tailored by polymersurface grafting.
Carrerre, N. +5 more
core +3 more sources
This paper report the synthesis of binary-patterned brushes, combining two distinctive surface initiated-polymerizations (SIP) on the basis of different propagating species: the SI Ring Opening Polymerization (ROP) of L-Lactide (LLA) and SI atom transfer
Olivier Aurore +3 more
doaj +1 more source
Poly(4-vinylpyridine-r-n-octadecyl acrylate) and poly(4-vinylpyridine-r-n-octadecyl methacrylate) were successfully synthesised via atom transfer radical polymerization (ATRP) using 10-phenylphenothiazine as the photo-induced catalyst.
Loc Tan Nguyen +3 more
doaj +1 more source

