Progress in the Design and Application of Chemical and Biological Sensors Based on Atom Transfer Radical Polymerization [PDF]
Atom transfer radical polymerization (ATRP) is a leading reversible deactivation radical polymerization method. It has become an emerging technology to synthesize well-defined, tailor-made polymers, promoting the development of advanced materials (e.g ...
Ning Xia +4 more
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Modern methods of controlled radical polymerization for obtaining branched polymers of acrylamide, acrylic acid and (met)acrylates [PDF]
A search and analysis has been carried out of English-language 2005–2020 scientifi c literature devoted to methods of obtaining branched (co)polymers of acrylamide, acrylic acid and (met)acrylates in order to obtain novel materials with ...
Bayburdov, Telman А. +1 more
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Nearly monodisperse unimolecular micelles via chloro-based atom transfer radical polymerization
Fabrication of unimolecular micelles with uniform sizes and well-controlled structure is currently a big challenge. Herein, we report an easy-to-handle protocol for the preparation of nearly monodisperse unimolecular micelles via atom transfer radical ...
Zepeng Li +12 more
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Impact of Oxygen and Sulfur Heteroatom Core Substitution on Catalyst Properties of Phenoxazines and Their Performance in Organocatalyzed Atom Transfer Radical Polymerization (O-ATRP). [PDF]
Lathrop JL +3 more
europepmc +2 more sources
Cytochrome C catalyzed oxygen tolerant atom-transfer radical polymerization
Atom-transfer radical polymerization (ATRP) is a well-known technique for controlled polymer synthesis. However, the ATRP usually employed toxic heavy metal ionas as the catalyst and was susceptible to molecular oxygen, which made it should be conducted ...
Peng-Cheng Xie +7 more
doaj +1 more source
Preparation of Polyacrylamide with Improved Tacticity and Low Molecular Weight Distribution [PDF]
Polyacrylamide with improved tacticity and low molecular weight distribution was obtained via stereospecific atom transfer radical polymerization (ATRP) using the mixture of Lewis acids Y(OTf)3 and AlCl3 in a certain ratio as stereospecific catalyst and ...
Jiang Jianguo +4 more
doaj +1 more source
Preparation and Characterization of Hyperbranched Polystyrene Nanocomposite Synthesized by Living Radical Polymerization and Solution Intercalation Method [PDF]
A copolymer of styrene and methyl styrene was synthesized by nitroxide - mediated “living” free radical polymerization )NMP). N-Bromosuccinimide was used as a brominating agent to obtain a copolymer with bromine as its end group.
Mojtaba Abbasian +3 more
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Preparation of Polystyrene Nanocomposite by In Situ Atom Transfer Radical Polymerization: Study of Polymerization Kinetics in the Presence of Clay [PDF]
Styrene nanocomposites were synthesized by in-situ atom transfer radical polymerization at 110oC. The variations of monomer conversion and the linearity of semilogarithmic kinetic plot, some signs of living polymerizationand constant radical ...
H. Roghani-Mamaqani +3 more
doaj +1 more source
Iron Catalysts in Atom Transfer Radical Polymerization
Catalysts are essential for mediating a controlled polymerization in atom transfer radical polymerization (ATRP). Copper-based catalysts are widely explored in ATRP and are highly efficient, leading to well-controlled polymerization of a variety of ...
Sajjad Dadashi-Silab +1 more
doaj +1 more source
A Comparative Study between FRP and ATRP of Styrene by Monte Carlo Simulation: Effect of Free Radical Mobility [PDF]
Styrene polymerization through FRP and ATRP methods was carried out at 110oC, while in-depth studies were performed by Monte Carlo simulation.The changes in monomer conversion, initiator concentration, average molecular weight, and polydispersity index ...
M. Najafi +3 more
doaj +1 more source

