Reversing Blocking Order of Trithiocarbonate‐Mediated RAFT Polymerizations Using Photocatalysis
Acrylic‐methacrylic block copolymers have limited accessibility due to monomer order requirements in reversible‐deactivation radical polymerization techniques leading to a vast landscape of block copolymers being understudied. Using unique PET‐RAFT polymerization conditions, a controlled chain extension of poly(methyl acrylate) with methyl methacrylate
Jared G. Baker+7 more
wiley +2 more sources
Block and star block copolymers by mechanism transformation. II. Synthesis of poly(DOP-b-St) by combination of ATRP and CROP [PDF]
Yijin Xu, Cai‐Yuan Pan, Lei Tao
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Diverse reactivity of maleimides in polymer science and beyond
This mini‐review provides a thorough overview of maleimide chemistry, highlighting its diverse reactivity in polymer and materials science applications. Abstract Maleimides are remarkably versatile functional groups, capable of participating in homo‐ and copolymerizations, Diels–Alder and (photo)cycloadditions, Michael additions, and other reactions ...
Bruce E Kirkpatrick+2 more
wiley +1 more source
Preparation of Polyisobutene-graft-Poly(methyl methacrylate) and Polyisobutene-graft-Polystyrene with Different Compositions and Side Chain Architectures through Atom Transfer Radical Polymerization (ATRP) [PDF]
Sung Chul Hong+2 more
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Synthesis of Poly(Itaconate)s With High Monomer Conversion Applying Emulsion Polymerization
Itaconic acid and its derivatives are a promising and bio‐based substitute for oil‐based polymers such as acrylates. In this study, the optimization of polymerization of itaconic acid esters is described by applying emulsion polymerization leading to high reaction conversions and low residual monomer contents. ABSTRACT Itaconic acid and its derivatives
S. Charlotte Fischer von Mollard+5 more
wiley +1 more source
Solvent Effects on the Synthesis of Poly(methyl methacrylate) by Atom-Transfer Radical Polymerization (ATRP) [PDF]
José de la Fuente+3 more
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Two approaches to introduce conductivity and high enzyme loading efficiency into polymer brush functionalized particles are pursued. First, conductive nanoparticles and laccase are incorporated into PDMAEMA brushes on silica particles. Second, conductive silver particles grafted with PDMAEMA brushes are loaded with laccase.
Hongtao Cai+5 more
wiley +1 more source
Atom transfer radical polymerization (ATRP) with dual photoredox/copper catalysis combines the advantages of photo-ATRP and photoredox-mediated ATRP, utilizing visible light and ensuring broad monomer scope and solvent compatibility while minimizing side
Woojin Jeon+2 more
doaj +1 more source
Preparation and thermal properties of block copolymers of PDMS with styrene or methyl methacrylate using ATRP [PDF]
David W. Brown
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Self‐assembled particles from linear‐bottlebrush copolymers exhibit distinct internal morphology and dis‐assembly behavior. ABSTRACT Linear–bottlebrush (LB) amphiphilic block copolymers offer a unique platform for designing self‐assembled nanostructures with tunable responsiveness.
Shin Takano, Markus Müllner
wiley +1 more source