Results 61 to 70 of about 22,958 (282)

Oligomeric alkylpyridinium surfactants prepared via ATRP [PDF]

open access: yese-Polymers, 2011
AbstractA series of oligomeric alkylpyridinium surfactants were prepared directly in aqueous media by atom transfer radical polymerization (ATRP) of a surfmer, 4- vinyl-N-dodecylpyridinium bromide, and their surface activities were examined in comparison with the surfmer.
Xin Su   +4 more
openaire   +1 more source

Synthesis and characterization of amphiphilic nitroxide 1,1,3,3–tetraethylisoindoline–2–oxyl–5–sodium sulfonate (TEIOSNa)

open access: yesThe Canadian Journal of Chemical Engineering, EarlyView.
Abstract The synthesis and characterization of an amphiphilic nitroxide to be used as a controlling agent in a nitroxide‐mediated living radical polymerization in aqueous dispersion media is presented. In the first stage of nitroxide synthesis (phthalimide protection), two reaction methods were employed: traditional and microwave.
Enrique García‐Leal   +3 more
wiley   +1 more source

Efficient Synthesis of Narrowly Dispersed Brush Polymers via Living Ring-Opening Metathesis Polymerization of Macromonomers [PDF]

open access: yes, 2009
Various macromonomers (MMs) were efficiently synthesized through the copper-catalyzed “click” coupling of a norbornene moiety to the chain end of poly(methylacrylate), poly(t-butylacrylate), and polystyrene that were prepared using atom transfer radical ...
Grubbs, Robert H.   +2 more
core   +1 more source

Light-Controlled Radical Polymerization: Mechanisms, Methods, and Applications [PDF]

open access: yes, 2015
The use of light to mediate controlled radical polymerization has emerged as a powerful strategy for rational polymer synthesis and advanced materials fabrication.
Chen, Mao   +2 more
core   +1 more source

Fluoro‐Functionalized Polyether Electrolytes Enabling High‐Energy‐Density Solid‐State Lithium‐Metal Batteries

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Fluoro‐functionalized polyether electrolytes, which combine fluorine‐ and ether‐containing groups, achieve enhanced oxidative stability, high ionic conductivity, and superior interfacial stability. Due to their non‐flammability, remarkable flexibility, ease of processing, and design versatility, polymer‐based electrolytes containing polyethers have ...
Nannan Geng   +8 more
wiley   +1 more source

Kinetic Studies of Atom Transfer Radical Polymerisations of Styrene and Chloromethylstyrene with Poly(3-hexyl thiophene) Macroinitiator

open access: yesAdvances in Materials Science and Engineering, 2015
Poly(3-hexyl thiophene)-b-poly(styrene-co-chloromethylstyrene) copolymers, to be used as a prepolymer for preparing donor-acceptor block copolymers for organic solar cells, have been synthesised by reacting P3HT macroinitiators with styrene and ...
Nattawoot Rattanathamwat   +4 more
doaj   +1 more source

“One-pot” dispersion ATRP and alkyne-azide Huisgen’s 1,3-dipolar cycloaddition in supercritical carbon dioxide: towards the formation of functional microspheres [PDF]

open access: yes, 2010
Functional polymers were successfully prepared in scCO2 by combining alkyne-azide 1,3-dipolar Huisgen’s cycloaddition and dispersion ATRP in a “one pot” process using new perfluorinated polymeric amino-based ligands that had a dual role, i.e.
Calberg, Cédric   +3 more
core   +1 more source

Recent Advances in Conjugated Microporous Polymers for Photocatalysis: Mechanism, Synthesis and Applications

open access: yesExploration, EarlyView.
Conjugated microporous polymers (CMPs) have attracted more and more attention as new photocatalysts due to their unique advantages such as high performance, long stability and strong light absorption. This review summarizes the application of CMPs as a photocatalyst in recent years and introduces the catalytic mechanism.
Dun Zhou   +5 more
wiley   +1 more source

Direct introduction of nitrogen and oxygen functionality with spatial control using copper catalysis. [PDF]

open access: yes, 2018
Synthetic chemists have spent considerable effort optimizing the synthesis of nitrogen and oxygen containing compounds through a number of methods; however, direct introduction of N- and O-functionality remains challenging.
Fisher, David J   +4 more
core  

Polymer brush collapse under shear flow

open access: yes, 2017
Shear responsive surfaces offer potential advances in a number of applications. Surface functionalisation using polymer brushes is one route to such properties, particularly in the case of entangled polymers.
Adlmann, Franz A.   +8 more
core   +3 more sources

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