Results 141 to 150 of about 5,372 (258)
A potyvirus‐derived virus‐like nanoparticle (VLP) interferes in the transmission by aphids of the non‐circulative plant viruses turnip mosaic virus (TuMV, Potyvirus), zucchini yellow mosaic virus (ZYMV, Potyvirus), and cucumber mosaic virus (CMV, Cucumovirus) is also observed. The construct, that consisted of a fusion between a modified TuMV HC‐Pro and
Aranzazu Moreno +7 more
wiley +1 more source
Evidence for a Cu(II)‐Catalysed CuAAC Reaction: A Combined Experimental and Computational Study
A new mechanistic pathway for the CuAAC reaction has been found to operate under specific reaction conditions. The pathway is catalysed by Cu(II) through a self‐assembled dinuclear Cu(II) complex that incorporates the triazole product. Computational analysis and assessment of generality are reported.
Matthew J. Andrews +12 more
wiley +2 more sources
Proton‑transfer catalysis controls acylsemicarbazide dissociation, linking proton affinity to exchange kinetics and enabling predictive design of robust, tunable dynamic covalent networks. ABSTRACT We provide design principles for predicting bond exchange kinetics in acylsemicarbazide (ASC)‐based systems that can be applied to tuning the properties of ...
Siebe Lekanne Deprez +6 more
wiley +1 more source
Microphase assisted "autocatalysis"
The mathematical model developed in this study considered reaction, crystallization, and microphase processes simultaneously to describe "autocatalytic" microphase action more effectively. Simulations were performed to determine the effect of crystal growth rates, nucleation rates and the initial crystal size distribution on the overall reaction rate ...
openaire +3 more sources
Computational study reveals a two‐step decomposition of alkylcopper complexes into (partially) reduced Cu clusters, proposed as prenucleation species for Cu(0) nanoparticle synthesis. Cu‐hydride intermediates and multinuclear centers lower reaction barriers.
Marina Descoubes, Hélène Gérard
wiley +1 more source
The article describes the synthesis and molecular transformations of a silica‐supported bis(phosphine)methylplatinum(II) complex under reactive (H2, CO) and inert gas atmospheres. The focus lies on the stabilizing effect of the sterically non‐demanding trimethylphosphine ligand, which alters the reactivity of the surface sites, compared to other ...
Lea S. Kopietz +6 more
wiley +1 more source
Discrete DSC and rheological data are transformed into continuous compositional Time–temperature–transformation (TTT) diagrams through physics‐informed Gaussian Process Regression. The proposed framework quantitatively predicts post‐gel processing windows across temperature and nanofiller composition, providing a practical route for accelerated design ...
Otávio Bianchi +6 more
wiley +1 more source
Macro‐ and Micromechanical Deformations and Failure of Recycled PET/Flax Polyester Biocomposites
Macro‐ and Micromechanical Deformations and Failure of Recycled PET/Flax Polyester Biocomposites. ABSTRACT Environmental sustainability has become a global priority aimed at reducing waste generation and dependence on fossil resources. This study reports on the development of sustainable biocomposites by combining flax woven fabrics (2, 4, and 6 plies)
Bianca Dal Pont +6 more
wiley +1 more source
Toward Ideal Proximity‐Driven Reactions in Chemical Biology
Building on established principles of molecular templation, this perspective explores how molecular recognition can control chemical reactivity in space and time and outlines the design principles of an ideal proximity‐driven reaction for chemical biology.
Dominik Schauenburg
wiley +1 more source
The diverse effects of side reactions on the persistence of autocatalytic cycles. [PDF]
Peng Z, Spencer E, Baum D.
europepmc +1 more source

