Results 81 to 90 of about 2,636 (212)

Overcoming the Ethanol/Water Azeotrope: A Review on Advanced Technologies for Bioethanol Purification

open access: yesEngineering Reports
Ethanol dehydration is a crucial task in the production of bioethanol for fuel applications. Such separation represents a challenge due to the presence of the ethanol‐water azeotrope.
Fernando Israel Gómez‐Castro   +8 more
doaj   +1 more source

Using Dialkylimidazolium Ionic Liquids To Break the Methanol + Methyl Acetate Azeotrope

open access: yes, 2019
Separating mixtures that form azeotropes or have relative volatilities close to 1.0 has always been a challenging problem. Conventional distillation cannot yield high purity products for these systems, so separating them often becomes a capital- and ...
Joshua M. Winnert (7945424)   +5 more
core   +1 more source

The Methanol-Trimethoxyborane Azeotrope as a Solvent for Acid-Catalyzed Reactions. Methyl Esterification [PDF]

open access: yes, 1977
Carboxylic acids UIIldergo a rapid and complete acid-catalyzed methyl esterification in the methanol-trimethoxyborane azeotrope. The reaction is first order in cariboxylic acid and first order in strong acid catalyst.
Kantner, S. S., Kreevoy, M. M.
core   +1 more source

Simulation and optimization of a modified salt extractive distillation process for the production of anhydrous ethanol

open access: yesResults in Chemistry
Producing anhydrous ethanol through ethanol dehydration is challenging due to the formation of an ethanol-water azeotrope. Traditional methods use carcinogenic liquid separating agents like benzene to break this azeotrope.
Manish Kumar Yadav   +5 more
doaj   +1 more source

Dehydration of an azeotrope of ethanol/water by sodium carboxymethylcellulose membranes cross-linked with organic or inorganic cross-linker

open access: yeseXPRESS Polymer Letters, 2010
To control the swelling of sodium carboxymethylcellulose (CMCNa) membranes, mixtures of CMCNa and glutaraldehyde (GA) and mixtures of CMCNa as an organic component and tetraethoxysilane (TEOS) as an inorganic component were prepared, and CMCNa/GA cross ...
doaj   +1 more source

Thermodynamic and topological analysis of the formation of internal tangential azeotropes in binary two-phase systems

open access: yesТонкие химические технологии, 2015
The analysis of properties of the internal tangential azeotrope that leads to biazeotropy as a result of the bifurcation was carried. Internal tangential azeotrope has a number of specific properties, some of which is identical to usual binary azeotropes,
L. A. Serafimov   +2 more
doaj  

Sustainable Approach to Waste-Minimized Sonogashira Cross-Coupling Reaction Based on Recoverable/Reusable Heterogeneous Catalytic/Base System and Acetonitrile Azeotrope

open access: yes, 2016
In this contribution, we present a chemically efficient and sustainable protocol for the palladium-catalyzed copper-free Sonogashira cross-coupling reaction, based on the use of a heterogeneous catalytic system.
GRUTTADAURIA, Michelangelo   +21 more
core   +1 more source

The diagrams of -1-lines for ternary

open access: yesТонкие химические технологии, 2011
Different properties and types of α-1-lines for ternary zeotropic mixtures and ternary mixtures with one binary azeotrope are presented in a brief literature review.
K. Yu. Tarkhov, L. A. Serafimov
doaj  

The conditional extremum lines research for the soperfluous gibbs potential surface for stratified systems

open access: yesТонкие химические технологии, 2010
The possibility of a technique application revealing the probable existence area triple azeotrope, based on analysis of concentration dependences of activity coefficient complexes in liquid phases, in stratified zeotropic mixtures, mixtures containing ...
А. V. Frolkova   +2 more
doaj  

Tangential azeotropy in binary constituents of ternary azeotropic mixtures.

open access: yesТонкие химические технологии, 2009
Transformations of phase diagrams of vapor-liquid equilibrium for ternary systems containing single triple azeotrope are considered. The considered transformations include the stage of border tangential azeotropy.
L. A. Serafimov   +2 more
doaj  

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