Results 271 to 280 of about 236,434 (328)

Synthesis of 4-azido sialic acid for testing against Siglec-7 and in metabolic oligosaccharide engineering. [PDF]

open access: yesRSC Chem Biol
Gray TE   +8 more
europepmc   +1 more source

A Sydnonimine-based Click-and-Release Approach to Cyclic Products. [PDF]

open access: yesChemistry
Force G   +5 more
europepmc   +1 more source

High‐Pressure Synthesis of Nitrogen‐Rich Y(N5)3·N2 Pentazolate with Perovskite Topology

open access: yesAngewandte Chemie International Edition, EarlyView.
Yttrium pentazolate, Y(N5)3·N2, with an exceptionally high nitrogen‐to‐metal ratio of 17:1 and perovskite topology, was synthesized from yttrium and nitrogen at 125 GPa and 3000 K in a laser‐heated diamond anvil cell. Abstract The discovery and stabilization of the cyclo‐N5⁻ anion have introduced a class of pentazolate compounds with significant ...
Andrey Aslandukov   +8 more
wiley   +1 more source

Reactivity of Pnictaalumenes Towards 1,3‐Dipole Molecules

open access: yesAngewandte Chemie International Edition, EarlyView.
Pnictaalumenes with a Pn═Al multiple bonds undergo azide or diazoalkene insertions rather than [3+2] cycloadditions. This results in AlN2P heterocycles, which show a great structural variety depending on the sterics of the azide. With TMS‐diazoalkane, thermal rearrangements afford rare cyanidoaluminates. Abstract Alkynes undergo 1,3‐dipolar cyclization
Tim Wellnitz   +7 more
wiley   +1 more source

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