Results 281 to 290 of about 286,921 (352)

Computational Study of Ignored Pericyclic Reactions: Rearrangements of 1,2‐Bis(Diazo)Alkanes to 1,2,3,4‐Tetrazines and Subsequent Fragmentations

open access: yesAngewandte Chemie, EarlyView.
DFT calculations of the 8π‐electrocyclization of 1,2‐bis(diazo)alkanes and of other bis‐1,3‐dipoles reveal that this process can establish a so far ignored route to heterocycles such as 1,2,3,4‐tetrazines. Alternative reaction channels via carbenes or nitrenes leading to fragmentation products are discussed.
Hans‐Ulrich Reissig   +1 more
wiley   +1 more source

Heat up, silence on: IDO1 gene silencing in THP-1-derived dendritic cells triggered by magnetic hyperthermia. [PDF]

open access: yesCancer Immunol Immunother
Ferreira D   +7 more
europepmc   +1 more source

Structural Dependence of Catenand Effect: Thermodynamic and Kinetic Modulation of Catenane Coordination Properties via Ring‐size and Exocyclic Substituent Variation

open access: yesAngewandte Chemie, EarlyView.
By modifying ring size and exocyclic substituents, effects of ligand interlocking on metal coordination features is explored. Through systematic analysis of CuI catenanes, relationship between structural parameters of the interlocked ligands and coordination properties like geometry, stability, and reactivity is established.
Yulin Deng   +8 more
wiley   +1 more source

Synthesis and Application of Bioactive N‐Functionalized Aziridines

open access: yesAngewandte Chemie, EarlyView.
This review discusses modern synthetic methods for the preparation of aziridine‐containing small molecules, including biocatalytic, electrocatalytic, and photocatalytic strategies. We highlight the compatibility of various synthetic methods with control of the exocyclic N‐substituent.
Hao Tan   +4 more
wiley   +1 more source

NIR‐Activatable, Sequence‐Specific Metal‐Nucleic Acid Scaffolds for Responsive Uncaging

open access: yesAngewandte Chemie, EarlyView.
We demonstrate that long‐range nucleic acid‐mediated electron transfer can drive Pt(IV) photoreduction, establishing a new class of metal‐nucleic acid scaffolds capable of “responsive uncaging,” where hybridization with target DNA or miRNA directly triggers payload release under NIR irradiation.
Arpit Sharma   +6 more
wiley   +1 more source

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