Results 321 to 330 of about 227,350 (349)
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Azide Phosphoramidite in Direct Synthesis of Azide-Modified Oligonucleotides
Organic Letters, 2014Azide and phosphoramidite functions were found to be compatible within one molecule and stable for months in solution kept frozen at -20 °C. An azide-carrying phosphoramidite was used for direct introduction of multiple azide modifications into synthetic oligonucleotides.
Maksim Navakouski +6 more
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Nature, 1931 WE have just seen Dr. Sutton's communication on the “Structure of the Azides, from their Electric Dipole Moments”.1 We also have measured the dipole moments of phenylazide, p-chlorphenylazide, and p-bromphenylazide and found the values 1.55, 0.47, and 0.64 × 10â18 e.s.u., respectively, in good agreement with Dr. Sutton's data.
Willibald Schütz, Ernst D. Bergmann
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Solubility of Sodium Azide and Alpha-Lead Azide.
Journal of Chemical & Engineering Data, 1966The solubility of sodium azide was determined in water and in 40, 60, 80, and 95.5% ethanol-water mixtures, respectively. The solubilities were first determined by a synthetic method (9) which involved the preparation of a solution of known composition, the saturation point of which was determined by varying the temperature.
Eugene Lieber +3 more
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Inorganic Chemistry, 2008
Ionic liquid azides from azidoethyl, alkyl, and alkenyl substituted derivatives of 1,2,4- and 1,2,3-amino-triazoles were prepared and examined for the first time to investigate their structural and physical properties. All reported salts possess melting points below 100 degrees C.
Leslie Hudgens +7 more
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Ionic liquid azides from azidoethyl, alkyl, and alkenyl substituted derivatives of 1,2,4- and 1,2,3-amino-triazoles were prepared and examined for the first time to investigate their structural and physical properties. All reported salts possess melting points below 100 degrees C.
Leslie Hudgens +7 more
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Angewandte Chemie, 2023
AbstractAzide compounds are widely used and especially, polymers bearing pendant azide groups are highly desired in numerous fields. However, harsh reaction conditions are always mandatory to achieve full azidation, causing severe side reactions and degradation of the polymers.
Chi Zhang +8 more
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AbstractAzide compounds are widely used and especially, polymers bearing pendant azide groups are highly desired in numerous fields. However, harsh reaction conditions are always mandatory to achieve full azidation, causing severe side reactions and degradation of the polymers.
Chi Zhang +8 more
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1994
Hydrazine hydrate (1.67 ml = 1.72 g, 34 mmol) is added to a solution of N-benzyloxycarbonyl-S-benzyl-l-cysteinyl-l-seryl-l-histidine methyl ester [1, 2] (5.84 g, 10 mmol) in methanol [3] (50 ml) and the reaction mixture is kept at room temperature for 3 days [4].
Miklos Bodanszky, Agnes Bodanszky
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Hydrazine hydrate (1.67 ml = 1.72 g, 34 mmol) is added to a solution of N-benzyloxycarbonyl-S-benzyl-l-cysteinyl-l-seryl-l-histidine methyl ester [1, 2] (5.84 g, 10 mmol) in methanol [3] (50 ml) and the reaction mixture is kept at room temperature for 3 days [4].
Miklos Bodanszky, Agnes Bodanszky
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Carbohydrate Polymers, 2006
Starch is an inexpensive commodity that has been used for non-food purposes for many years. Some of these uses include cross-linked starches that are synthesized with a variety of multifunctional reagents. One unexplored possibility is the use of azides for cross-linking.
Gregory M. Glenn +7 more
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Starch is an inexpensive commodity that has been used for non-food purposes for many years. Some of these uses include cross-linked starches that are synthesized with a variety of multifunctional reagents. One unexplored possibility is the use of azides for cross-linking.
Gregory M. Glenn +7 more
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Chemistry – A European Journal, 2016
AbstractPure, solvent‐free Zn(N3)2 was prepared by reaction of diethyl zinc and hydrazoic acid in aprotic solvents. The single‐crystal structure determination, along with the comprehensive characterization of α‐Zn(N3)2 and two metastable polymorphs, could be achieved for the first time.
Alexander Villinger, Axel Schulz
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AbstractPure, solvent‐free Zn(N3)2 was prepared by reaction of diethyl zinc and hydrazoic acid in aprotic solvents. The single‐crystal structure determination, along with the comprehensive characterization of α‐Zn(N3)2 and two metastable polymorphs, could be achieved for the first time.
Alexander Villinger, Axel Schulz
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Structure of azide methemoglobin
Journal of Molecular Biology, 1979Abstract We have compared the structures of horse azide methemoglobin and methemoglobin (MetHb) at 2.8 A resolution by X-ray difference Fourier analysis. Of four low-spin liganded Hb derivatives (nitric oxide Hb, carbon monoxide Hb, cyanide MetHb, and azide MetHb), azide MetHb is closest in structure to MetHb.
James F. Deatherage +2 more
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Sensitized photodecomposition of phenyl azide and α-naphthyl azide
J. Chem. Soc., Faraday Trans. 2, 1972The photodecomposition of phenyl azide and α-naphthyl azide can be induced by triplet sensitizers (aromatic ketones) and by singlet sensitizers (aromatic hydrocarbons). From a comparison of transfer rates with sensitizer energies, and from the spectra and the oxidation potentials of the azides, it appears that two different mechanisms may operate ...
L. J. Leyshon, A. Reiser
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