Results 41 to 50 of about 3,434 (226)

Synthesis of Z-Protected Aib- and Phe(2Me)-Containing Pentapeptides and Their Crystal Structures [PDF]

open access: yes, 2014
A series of pentapeptide derivatives containing alpha,alpha-disubstituted alpha-amino acids have been prepared by a combination of the 'azirine/oxazolone method' and segment condensations.
Arnhold, Franziska S   +2 more
core   +1 more source

Bildung eines Azacyclols durch transanulare Ringkontraktion

open access: yesCHIMIA, 1988
Reaction of 3-dimethylamino-2,2-dimethyl-2H-azirine (1) with phthalimide (8) in polar solvents yields the (1:1)-adduct 2-dimethylamino-9b-hydroxy-3,3-dimethyl-5,9b-dihydro-3H-imidazo[2,1-a]isoindol-5-one (10).
Marlise Schläpfer-Dähler   +4 more
doaj   +1 more source

2-Methylsulfanylbenzo[f]isoquinoline [PDF]

open access: yes, 2015
S-Methylation of a 4-(naphth-2-yl)-β-thiolactam gives an intermediate 4-(naphth-2-yl) substituted 1-azetine which undergoes a [2+2] ring-opening followed by electrocyclic ring closure of the resulting 2-azadiene to give a benzo[f ...
Hemming, Karl   +2 more
core   +2 more sources

2-Oxo-4H-imidazolium-1-acetamidate, neue stabilisierte Dipole aus Aminoazirinen und NH-aciden Heterocyclen

open access: yesCHIMIA, 1985
3-Dimethylamino-2,2-dimethyl-2H-azirine (1) and 5-trifluoromethyl-1,3,4- oxadiazol-2(3H)-on (9) in 2-propanol react already at room temperature to give the dipolar compound 10 in reasonable yield (Scheme 4).
Roland Prewo   +2 more
doaj   +1 more source

Benzene derivatives produced by Fusarium graminearum — Short communication [PDF]

open access: yes, 2015
Using NMR spectroscopy benzene derivatives were detected in mycelia of Fusarium graminearum, a pathogen of wheat and maize. In previous studies F. graminearum was found to cause cancer to humans and benzene derivatives were detected in breath of cancer ...
Ntushelo, Khayalethu   +1 more
core   +1 more source

Rapid and Bifunctional Chemoselective Metabolome Analysis of Liver Patient Samples Using the Reagent 4-Nitrophenyl-2H-azirine.

open access: yesAngewandte Chemie
Primary sclerosing cholangitis (PSC) is a chronic inflammatory disease of the bile ducts that has been associated with diverse metabolic carboxylic acids. Mass spectrometric techniques are the method of choice for their analysis.
Weifeng Lin   +5 more
semanticscholar   +1 more source

Neuere Methoden zur Ringerweiterung organischer Verbindungen

open access: yesCHIMIA, 1980
The actual interest in the construction of cyclic compounds via ring expansion reactions is demonstrated in the first chapter by means of typical examples.
Heinz Heimgartner
doaj   +1 more source

CuH-Catalyzed Regioselective Intramolecular Hydroamination for the Synthesis of Alkyl-Substituted Chiral Aziridines [PDF]

open access: yes, 2017
This report details a general and enantioselective means for the synthesis of alkyl-substituted aziridines. This protocol offers a direct route for the synthesis of alkyl-substituted chiral aziridines from achiral starting materials.
Wang, Haoxuan   +2 more
core   +1 more source

Kristallstruktur eines 2-Dimethylamino-3,3-dimethyl-4(3H)-pyridons

open access: yesCHIMIA, 1982
3-Dimethylamino-2,2-dimethyl-2H-azirine (1) reacts with alkyl phenyl substituted cyclopropenones 2 in benzene at 130 °C to give a mixture of the two isomeric 4(3H)-pyridones 3 and 4, resulting from a nucleophilic attack at C(2) and C(1) of the ...
Jost H. Bieri   +2 more
doaj   +1 more source

Global membrane protein interactome analysis using in vivo crosslinking and MS-based protein correlation profiling [PDF]

open access: yes, 2016
We present a methodology using in vivo crosslinking combined with HPLC-MS for the global analysis of endogenous protein complexes by protein correlation profiling. Formaldehyde crosslinked protein complexes were extracted with high yield using denaturing
Andersen   +52 more
core   +2 more sources

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