A set of 3‐sulfonyl‐azaspiro[4.5]trienones have been obtained via a metal‐ and photocatalyst‐free visible‐light‐driven dearomative strategy. The protocol exploits arylazo sulfones, which act simultaneously as the light absorber and sulfonyl‐radical source, enabling ipso‐spirocyclization of differently substituted N‐aryl propiolamides.
Luca Nicchio +5 more
wiley +1 more source
1,2‐Diazetidines − Structure, Synthesis, and Functionalization
1,2‐Diazetidines are saturated four‐membered heterocycles featuring two adjacent nitrogen atoms. Despite recent advances in their synthesis and promising potential in medicinal chemistry, the chemistry of these cyclic hydrazines remains underexplored.
Stefan Roesner
wiley +1 more source
Preparation and Antitumor Activity of METTL3 SiRNA Nanoparticles Carried by Hypoxia Sensitive Polymer (mPEG-Azo-PEI). [PDF]
Yin Z +7 more
europepmc +1 more source
Recent Progress on Enzyme Immobilization: Materials, Strategies, and Applications
Enzyme immobilization technology has undergone substantial evolution driven by advances in materials science. This review systematically examines the recent advances in enzyme immobilization since 2024, with a focused analysis of five major categories of enzyme carriers including covalent organic framework, metal‐organic frameworks, polymers, carbon ...
Shuran Wang +7 more
wiley +1 more source
High-Stability Lithium Metal Batteries Enabled by AZO-Modified Separators. [PDF]
Hong S, Tan R, Li J, Huang J, Song W.
europepmc +1 more source
Material design strategies for flexible n‐type polymer semiconductors
This Perspective surveys recent progress in flexible n‐type polymer semiconductors, emphasizing the interplay between molecular design and microstructure control. It outlines strategies including backbone and side‐chain engineering, multilevel microstructure optimization, to maintain charge‐transport pathways under mechanical deformation.
Xiao‐Yan Zhang +4 more
wiley +1 more source
Porous Organic Polymers with Azo, Azoxy, and Azodioxy Linkages: Design, Synthesis, and CO<sub>2</sub> Adsorption Properties. [PDF]
Kodrin I, Biljan I.
europepmc +1 more source
Mechanical stability in flexible perovskite solar cells: Interface engineering and device design
Statistics of the improvement methods for f‐PSCs. Abstract Flexible perovskite solar cells (f‐PSCs) demonstrate significant potential for application in next‐generation wearable electronic devices and photovoltaic building integration due to their high power conversion efficiency and excellent power‐to‐weight ratio. However, the inherent brittleness of
Hong‐Yi Hou +3 more
wiley +1 more source
Optical control of the cardiac rhythm with photoswitchable Na<sub>V</sub>1.5 channel blockers. [PDF]
Liu S +13 more
europepmc +1 more source
Memory of Chirality in Radical Addition–Translocation–Cyclization Cascades
Radical addition–translocation–cyclization cascades of chiral alkynes show striking memory of chirality (MoC), with strong retention of configuration when fast, polarity favored cyclization are involved. The most effective system employs a highly electron‐poor pentafluorobenzenesulfonyl group.
Christian Simon Gloor +3 more
wiley +1 more source

