The excited‐state intramolecular proton transfer (ESIPT) photoswitch tpmSA, which features an oxygen−acceptor, exhibits higher photochromic contrast (ΔE*Lab>74) than its nitrogen‐acceptor Schiff base analogues (ΔE*Lab<30). Theoretical calculations indicate that tpmSA effectively suppresses GSIPT, thereby enhancing the contrast.
Yahui Chen +10 more
wiley +2 more sources
The Nonadiabatic Nature of the Substituent Effects in Azobenzene. [PDF]
van der Wal JJ +4 more
europepmc +1 more source
Molecular solar thermal energy storage (MOST) systems offer an approach to harnessing solar energy by converting, storing, and releasing it within chemical bonds. This study introduces ethynylene‐linked 1,2‐dihydro‐1,2‐azaborinines as highly promising candidates for MOST systems, exhibiting exceptional energy densities and extended storage times.
Ralf Einholz +3 more
wiley +1 more source
On the unexpected mechanism of isomerization in tautomerizable azo photoswitches. [PDF]
Hillel C +3 more
europepmc +1 more source
Struktureller Mechanismus eines Aktivitäts‐Photoschalters am β2‐adrenergen Rezeptor
Zeitaufgelöste Strukturen aus Messungen an Röntgen‐Freie‐Elektronen‐Lasern in Kombination mit zellulären Assays zeigen, wie der photoschaltbare β‐Blocker Photoazolol‐1 als Wirksamkeits‐Photoschalter der Funktion des β2‐adrenergen Rezeptor wirkt. Die lichtinduzierte Neupositionierung des Liganden verschiebt die Aktivität von inversem Agonistimus hin zu ...
Robin Stipp +29 more
wiley +1 more source
Azobenzene Reduction and Derivatization and Al-H Bond Insertion with β‑Diketiminate Gallium(I) Complexes. [PDF]
Dong H +5 more
europepmc +1 more source
Recent Advances in Stimuli-Responsive Membranes: From Supramolecular Design to Controlled Permeability. [PDF]
Moffa S +6 more
europepmc +1 more source
Connectivity-Rewired Construction of Hydrogen-Bonded Azo-Macrocycles Enables Photoswitchable Recognition of Lithium Ions. [PDF]
Tan C +7 more
europepmc +1 more source
Targeted Covalent Photoswitch for Two-Photon Control of Endogenous Receptors. [PDF]
Santini R +6 more
europepmc +1 more source
Precise modulation of MOF pore structures via functional group dimensions and spatial configuration for membrane separation. [PDF]
Sun W +6 more
europepmc +1 more source

