Directing the Mobility of Guest Molecules in Nanoporous Materials by Linearly Polarized Light. [PDF]
Najjar TA +11 more
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A Versatile Strategy for Light-Driven Active Transport of Ions. [PDF]
Yahaya S, Amano S, Nicoli F, Ragazzon G.
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Recent developments and future perspectives for photoresponsive-based gold nanoparticles (Au-NPs) and their biomaterial applications. [PDF]
Rajasekar M, Sivakumar M.
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Effect of a photoswitchable rotaxane on membrane permeabilization across lipid compositions. [PDF]
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On-Surface Synthesis of Azobenzene-Linked Porphyrin Derivatives. [PDF]
Isshiki Y +10 more
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A difluorocarbene-triggered annulation/ring expansion cascade <i>via</i> sequential single-atom-insertions: direct assembly of 2-fluoroquinazolinones from azo compounds. [PDF]
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Azobenzene as a photoswitchable mechanophore
Nature Chemistry, 2023Azobenzene has been widely explored as a photoresponsive element in materials science. Although some studies have investigated the force-induced isomerization of azobenzene, the effect of force on the rupture of azobenzene has not been explored. Here we show that the light-induced structural change of azobenzene can also alter its rupture forces ...
Yiran Li +17 more
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Enthalpies of formation of cis-azobenzene and trans-azobenzene
The Journal of Chemical Thermodynamics, 1992The standard (p° = 0.1 MPa) molar enthalpy of formation of crystalline trans-azobenzene was determined from its enthalpy of combustion in oxygen at 298.15 K measured by static-bomb calorimetry. The enthalpy of isomerization: ΔisomH°m(cr, cis → trans)/(kJ · mol−1) = -(49.1 ± 1.0), was measured by reaction-solution calorimetry: the isomerization was ...
A.R. Dias +7 more
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Mechano-isomerization of azobenzene
Chemical Communications, 2013We show that ultrasound-induced mechanical force isomerizes an azobenzene centered within a poly(methyl acrylate) polymer from cis to trans configuration without cleaving the azo bond. The isomerization rate was not altered by the polarity of the solvent indicating that the isomerization occurs through a non-polar, inversion transition state.
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